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Nuclear fission reactors, transmutation, and exotic isotopes
Dr. Jay Maron

Modern multipurpose reactors

The usual role of nuclear reactors is to produce electricity and heat, but they can do more, such as creating valuable elements by transmutation. They can transmute cheap tungsten into valuable rhenium, osmium, iridium, platinum, and gold. They can make medical isotopes and they can do neutron cancer therapy. They can make neutrons for scientific research. They can make nuclear batteries.

Modern reactors are unconditionally safe and meltdowns are impossible. They have a large array of safety features that old reactors don't. Modern reactors can be designed on a computer.

A reactor that uses fast neutrons can burn all the fuel, and a reactor that uses slow neutrons can only burn 10% of the fuel. Fast neutron reactors minimize radioactive waste.

Burnt fission fuel has valuable rhodium and palladium. The older the burnt fuel, the less radioactive it is, and the easier it is to extract these elements.


Generation IV nuclear reactors

Gas-cooled fast reactor

A prime goal of reactor design is maximizing temperature, which maximizes efficiency for producing electricity. Reactors are often used to produce hydrogen, which requires a temperature of 925 Celsius.

There are many designs for generation IV reactors, such as:

                                     Coolant  Neutrons  Fuel   Temperature
                                                        cycle    Celsius

Dual Fluid Reactor                   Lead      Fast     Closed    1000
Very High Temperature Reactor        Helium    Slow     Open      1000           Graphite moderator
Gas-cooled Fast Reactor              Helium    Fast     Closed     850
Lead-cooled Fast Reactor             Lead      Fast     Closed     800
Molten Salt Reactor                  Salt      Either   Closed     800
Supercritical Water-cooled Reactor   Water     Either   Either     625
Sodium-cooled Fast Reactor           Sodium    Fast     Closed     550

If all the fuel is burnt then the fuel cycle is "closed", and if not, it's "open".


Nuclear transmutation

The neutrons in a fission reactor can transmute elements, turning a cheap element into an expensive element. Reactors generate surplus neutrons for free.

Transmutation moves an element one spot to the right on the periodic table. Profitable transmutations are places on the periodic table where a high-value element is to the right of a low-value element. The most profitable transmutation is to turn tungsten into platinum, osmium, iridium, and gold. Another profitable transmutation is turning iodine into xenon.

Transmutation features a target element that is bombarded with neutrons, and the target should have a high neutron capture cross section. Tungsten and iodine qualify.

Molybdenum can capture neutrons and transmute to technetium, ruthenium, rhodium, and palladium, but it works poorly because molybdenum has a low capture cross section.


Tungsten transmutation

An example of transmutation is turning tungsten into rhenium. First tungsten absorbs a neutron.

Tungsten-186 + Neutron  →  Tungsten-187

Then it beta decays to rhenium with a half life of 24 hours.

Tungsten-187  →  Rhenium-187 + Electron

Rhenium-187 is stable, and more valuable than tungsten. Adding more neutrons converts rhenium to osmium. The full sequence is

Isotope    Neutron capture   Value
                barns        $/kg

Tungsten-186      35           32
Rhenium-187       76.4       1100
Osmium-188         4.7    1600000
Osmium-189        25      1600000
Osmium-190        13.1    1600000
Iridium-191      954       130000
Platinum-192      10.0      35000
Platinum-193       ?        35000        Half life of 50 years
Platinum-194       1.44     35000
Platinum-195      27.5      35000
Platinum-196        .72     35000
Gold-197          98.6      60000
Mercury-198        2.0         50

All isotopes in the sequence are stable except for platinum-192, which is effectable stable for transmutation purposes.

The neutron capture cross sections for tungsten and rhenium are large. Osmium's cross section is smaller, and this is fortunate because osmium is the most expensive element.

There are bottlenecks at platinum-194 and platinum-186, which have low cross sections.

Mercury is cheap, and so gold is the last useful element.

For tungsten, the isotopic abundances are

            Abundance   Cross section   Half life
                            barn           day

tungsten-180    .0012      60          Stable
tungsten-181   0            ?             121
tungsten-182    .265       20.7        Stable
tungtten-183    .143       10.1        Stable
tungsten-184    .307        1.70       Stable
tungsten-185   0            ?              75
tungsten-186    .286       35                .99

Iodine transmutation

When iodine transmutes to xenon, the xenon is easy to extract. It bubbles out.

Isotope   Neutron capture   Value
               barns        $/kg

Iodine-127      6.15        35
Xenon-128       8         1800
Xenon-128      21         1800
Xenon-128      26         1800
Xenon-128      85         1800
Xenon-128        .445     1800
Caesium-133    30.3      62000
Barium-134      2            1

Nuclear battery

Power

The best radioisotopes for power are:

           Half life   Power/mass   Energy  Gamma max   Formation rate
             year       Watt/kg      MeV       MeV         barn*year

Europium-152   13.5      1858       1.86      1.408          6005
Europium-155    4.76      705        .252      .147           312
Europium-154    8.59                1.968     1.274           216
Iridium-192      .202   29942       1.460      .613           134
Thulium-170      .352   33150        .968      .083            37.2
Thulium-171     1.91      606        .0968     .968            30.8
Caesium-134     2.06    15300       2.059      .80             21
Silicon-32    153         804       1.92                        2.22
Cobalt-60       5.27    19300       2.82      1.33              1.39
Strontium-90   28.9      2234       2.826                        .29
Plutonium-238  87.7       578       5.59      5.59               .125
Caesium-137    30.1       583       1.176      .66               -
Radium-226   1599         286      34.958     1.75               -

"Gamma" is the energy of the highest-energy gamma produced.

"Shielding" is the stopping length of the gamma in iridium.

"Formation rate" indicates how fast the isotope is formed in a fission reactor.


Human-safe battery

For radiation shielding, what matters is the highest-energy gamma produced.

            Half life   Power/mass   Decay   Gamma   Stopping   Formation  Decay
                                     energy   max     length      rate
              year       Watt/kg      MeV     MeV       mm      barn*year

Nickel-63      100.1        5.52   .017   .017      .004      2.5          β
Tritium         12.33     315      .0186  .0186     .005     71            β
Samarium-145      .931             .617   .061                 .022        EC
Promethium-145  17.7      131      .164   .072                 .022        EC
Platinum-193    50         17.5    .057   .076                3.8          EC
Thulium-171      1.91     606      .096   .096      .09      30.8          β
Europium-155     4.76     705      .252   .147              312            β

"Stopping length" is for iridium shielding.


Burnt fission fuel

Burnt fission fuel contains valuable palladium and rhodium. One kg of uranium costs $100 and produces $13000 of rhodium and $1600 of palladium. The elements produced by the fission of one kg of U-238 are:

               Mass   Value of   Value of element   Half life
                      element     in burnt fuel
               gram     $/kg          $/kg            year

Rhodium-103     26.1   500000      13000              Stable
Palladium-106   22.4    72000       1600              Stable
Xenon           44.6     1800         80              Stable    A mix of Xenon-131 and Xenon-132
Technetium-99   51.4        ?          ?              211000
Strontium-90    11.8        ?          ?                  28.8

Rhodium and palladium are important as catalysts. Technetium is important because there are no stable isotopes and it doesn't occur in nature. Strontium-90 is important because it can be used as a radioisotope battery. Technetium-99 and Strontium-90 don't have well-established market prices because they only come from fission reactors. Xenon is easy to extract because it's a noble gas.

The numbers are for fission by fast neutrons. Fission by slow neutrons produces similar numbers.


Fission products

Plutonium fission yields more rhodium and palladium than uranium fission. The fission products are nearly the same whether fast or slow neutrons are used. The fission products in ppt are:

              Half life   U-235  U-235  Pu-239  Pu-239   U-238
                year      slow   fast    slow    fast    fast

Rhodium-103    Stable     13.6   14.2    30.0    28.4    26.1
Palladium-106  Stable      3.6    4.2    37.2    36.6    22.4
Xenon          Stable     76.7   79.3    84.3    84.9    44.6
Technetium-99  211000     51.6   48.9    51.2    48.2    51.4

Commercial nuclear reactors

China has never shut down a nuclear reactor

Only China and India are engaged in large-scale reactor construction.

Nations that have shut down or aborted a large number of reactors include USA, UK, Germany, Japan, Russia, and Ukraine.

"Constructing" = Under construction
"Shut down" = Previously operational, then shut down
"Aborted" = Construction began but was aborted.

    Operational  Constructing  Shut  Aborted  Melted
                               down            down

  USA       94       2         41      2
  France    56       1         12
  China     51      20
  Russia    38       4          9     19
  Japan     33       4         23                3     Fukushima
  S Korea   24       4          2
  India     20      10          1
  Canada    19                  6
  Ukraine   15       2          3     13         1     Chernobyl
  UK        13       2         31      7
  Belgium    7                  1
  Czech Rep  6
  Germany    6                 30      4
  Pakistan   6       1
  Finland    4       1
  Hungar     4
  Slovakia   4       2          3
  Argentina  3       1
  Brazil     2       1
  UAE        1       3
  Iran       1       1
  Turkey             3
  Italy                         4     2
  N Korea            3          1     3

Superisotopes
Isotope production by present and future technology

Isotope catalog

Transuranics (actinides)
Suburanics
Island of stability


Isotope capabilities

Heat power
Low critical mass for fission
Spontanous fission
Fission afterburner rocket
Neutron multiplier
High-temperature heat


Isotope production
Neutron subtraction
Accelerator substitution
Alpha process
Chilled neutrons

Chief isotopes

Radioisotopes have more energy per mass than gasoline by a factor of 1 million. They can power an aircraft for 50 years and they power the Voyager spacecraft. They can make a fission bomb the size of a softball. Iron Man gadgets are possible with them. Important isotopes include:

          Half life (year)   Use

Tritium              12.3    Fusion fuel
Helium-3         Stable      Fusion fuel.  Dilution refrigerator.  Fission afterburner rocket

Uranium-235   704000000      Fission fuel.  Fission bomb
Plutonium-239     14100      Fission fuel.  Fission bomb

Thulium-170            .352  Power
Polonium-210           .379  Power.  Alpha rocket
Thorium-228           1.91   Power.  Alpha rocket
Thulium-171           1.91   Power.  Safe around humans because it requires low radiation shielding
Caesium-134           2.06   Power
Cobalt-60             5.27   Power
Europium-152         13.5    Power
Strontium-90         28.9    Power
Uranium-232          68.9    Power.  Alpha rocket
Plutonium-238        87.7    Power.  Alpha rocket
Radium-226         1599      Power.  Breeder for Thorium-228 and Uranium-232

Lithium-6        Stable      Fission afterburner rocket.  Fusion bomb
Boron-10         Stable      Fission afterburner rocket.  Cancer treatment
Beryllium-7            .146  Fission afterburner rocket
Sodium-22             2.602  Fission afterburner rocket

Americium-242m      141      Fission afterburner rocket
Californium-251     900      Fission afterburner rocket. Compact fission bomb. Large neutrons/fission
Californium-252       2.65   Spontaneous fission.        Compact fission bomb. Large neutrons/fission
Curium-250         8300      Spontaneous fission

Carbon-12        Stable      Isotopically-pure diamonds, nanotubes, and graphene
Carbon-14          5700      Low neutron capture cross section

Iridium-192            .202  Power at high temperature
Tantalum-182           .313  Power at high temperature
Tungsten-181           .332  Power at high temperature
Osmium-194            6.02   Power at high temperature

Nuclear battery

Voyager II
Plutonium-238

Isotope radioactivity can make electricity. The Voyager spacecraft are powered by plutonium-238.

The isotopes with high power/mass are:

                Half life    Heat      Decay      Decay    Obtainable by
                  year      Watt/kg                MeV     neutron transmutation

Californium-254       .166 11200000    Fission      207      *
Iridium-192           .202    29942    β              1.460  *
Scandium-46           .229   485000    β              2.366  *
Thulium-170           .352    33150    β               .968  *
Thulium-171          1.91       606    β               .0965 *
Caesium-134          2.06     15300    β              2.059  *
Californium-252      2.64     41400    α or Fission  12.33   *   α 96.9% (6.12 Mev). Fission 3.09% (207 MeV)
Cobalt-60            5.27     19300    β              2.824  *
Europium-154         8.59      3030    β              1.968  *
Tritium             12.33       315    β               .0186 *
Europium-152        13.5       1821    β & EC         1.86   *
Strontium-90        28.9       2234    β, &beta       2.826  *
Caesium-137         30.1        583    β              1.176  *
Plutonium-238       87.7        578    α              5.59   *
Americium-242m     141          725    2α            12.33   *
Silicon-32         153         1159    β,  β          1.92   *
Iridium-192m       241           72    IT, β          1.615  *
Curium-250        8300          170    Fission      148      *   Fission 74%, Alpha 18%, Beta 8%

Beryllium-7           .146  1822000    EC              .547
Hafnium-172          1.87     11700    EC             1.835
Hafnium-172          1.87     11700    EC             1.835
Sodium-22            2.6      68700    β+ or EC       2.842
Rhodium-101          4.07      9890    EC             1.980
Titanium-44         59.1       4318    EC, β+         3.798

Thorium-227           .0512 9194000    5α+2β          36.14
Uranium-230           .0554 9280000    6α+2β
Thorium-228          1.912   235000    5α+2β          34.784
Radium-228           5.75     90660    5α+4β          40.198
Actinium-227        21.8      21600    5α+3β          36.18
Uranium-232         68.9       7545    6α+2β          40.79
Radium-226        1599          286    5α+4β          34.958
Thorium-229       7917           57.7  5α+3β          35.366
Protactinium-231 32600           16.2  6α+3β          41.33
Thorium-230      75380            6.78 6α+4β          39.728

Human-safe battery

A battery that's around humans needs radiation shielding. Gammas are the most penetrating radiation, so what matters is the highest-energy gamma produced. Alpha and beta decay produce gammas by bremsstrahlung, and a charged particle can give all its energy to one gamma.

The isotopes with low-energy gammas are:

          Half life   Power/mass   Decay   Gamma   Stopping   Formation   Obtainable by   Decay
                                   energy   max     length      rate      neutron
            year       Watt/kg      MeV     MeV       mm      barn*year   transmutation

Nickel-63      100.1        5.52   .017   .017      .004      2.5           *           β
Tritium         12.33     315      .0186  .0186     .005     71             *           β
Rubidium-83       .236             .910   .0322               0                         EC
Samarium-145      .931             .617   .061                 .022         *           EC
Tantalum-179     1.82              .110   .065                0                         EC
Promethium-145  17.7      131      .164   .072                 .022         *           EC
Platinum-193    50         17.5    .057   .076                3.81          *           EC
Thulium-171      1.91     606      .096   .096      .09      30.8           *           β
Europium-155     4.76     705      .252   .147              312             *           β

"Gamma" is the energy of the highest-energy gamma produced.

"Stopping length" is the stopping length of the gamma in iridium. The radiation shield should be at least 10 times thicker than the stopping length.

"Formation rate" indicates of how fast it can be produced in a nuclear reactor. See the "Hurdle" section below.


Critical mass

The Demon Core. Almost a critical mass of plutonium-239.
Critical sphere size for californium-252
Critical sphere size for plutonium-239 (softball-sized)
Critical sphere size for uranium-235

Isotopes exist with a critical mass smaller than plutonium-239. The smallest critical mass is californium-252 at 2.7 kg. The critical sphere diameter is 6.9 cm, the size of a tennis ball.

               Half life   Critical  Critical  Density   Fission
                             mass    diameter             barn
                 year         kg        cm     gram/cm3

Californium-252          2.64    2.73    6.9       15.1         33
Californium-251        900       5.46    8.5       15.1       4894
Californium-249        351       6       9         15.1       1666
Curium-247        15700000       7       9.9       13.5         82

Plutonium-239        14100      10       9.9       19.8        748
Uranium-233         159000      15      11         19.1        536
Uranium-235      704000000      52      17         19.1        538

Natural uranium has a critical mass of 800 with heavy water moderator, and 10000 kg with graphite moderator.


Spontaneous fission

An isotope that sponteously fissions is a neutron source. The easiest such isotope to make is californium-252. The isotopes with a large spontaneous fission rate are:

                 Fission      Decay    Neutrons  Fission
                 half life  Half life    per     fraction
                  years       years    fission

Mendelevium-260       .0895      .0761            .85
Californium-254       .166       .166             .997
Californium-252     85.7        2.65     3.73     .0309
Curium-250       11200       8300        3.31     .74

Fission afterburner rocket

A fission thermal rocket uses a fission reactor to heat hydrogen exhaust. The higher the temperature, the faster the exhaust. The temperature limit is of the order 4000 Kelvin because this is the highest temperature for which solids exist. The material with the highest melting point is hafnium carbide at 4201 Kelvin.

A fission reactor can alternately heat exhaust by generating neutrons, which trigger fission in the exhaust. The neutrons are generated as a pulse and the exhaust is pulsed. The likelihood for a neutron to trigger fission is quantified as a "cross section". The isotopes with the largest fission cross section are:

               Half life   Fission   Energy   Quality   Neutron capture           Obtainable by
                 year       barn      MeV               output                    neutron transmutation

Americium-242m       141        7024  195       5640    Daughter nuclei + Neutrons   *
Californium-251      900        4894  207       3940    Daughter nuclei + Neutrons   *
Curium-245          8500        2161  198       1740    Daughter nuclei + Neutrons   *
Plutonium-239      14100         748  189        590    Daughter nuclei + Neutrons   *
Uranium-235    704000000         538  181        410    Daughter nuclei + Neutrons   *

Beryllium-7             .146   56800    1.644  11670    Lithium-7 + Proton
Sodium-22              2.602   27490    4.14    4948    Neon-22   + Proton
Helium-3          Stable        5333     .764   1020    Tritium   + Proton           *
Boron-10          Stable        3835    2.34     820    Lithium-7 + Alpha            *
Lithium-6         Stable         940    4.783    640    Tritium   + Alpha            *

Zirconium-88            .228  861000    8      77000    Zirconium-89   + Gammas
Gadolinium-157    Stable      259000    7.94   13020    Gadolinium-158 + Gammas      *
Gadolinium        Stable       49000    8       2500    Gadolinium-158 + Gammas      *    Natural composition

An isotope's quality as fission afterburner fuel is

Atomic mass number    =  M            Dimensionless
Fission energy        =  E            MeV
Fission cross section =  A            barns
Afterburn quality     =  Q = AE/M

Actinides

Many superisotopes are actinides. The orange line shows the isotopes can be produced by neutron capture.

Neutron capture transmutes an isotope one space to the right and beta decay transmutes an isotope one space up. Isotopes on or to the right of orange lines can be made with neutron transmutation and isotopes to the left of the lines can't. Elements that are made by neutron-transmutation tend to be neutron-heavy (neutronic), and elements that can't be made by neutron-transmutation tend to be proton-heavy (protonic).


Suburanics

Suburanics are the isotopes from radium to uranium. Many undergo 5 or 6 alpha decays, such as uranium-232. This is the red line in the plot.


Nuclear island of stability

There is a hypothetical "island of stability" around atomic number 112 where isotopes may be long-lived. A second island may exist at atomic number 126.

Experiments can only measure the longest-lived isotope up to a proton number of 105, and beyond that we plot theory. Theoretical half lives are uncertain by an order of magnitude.

It's possible that for large nucleon number, larger than around 300, that the nucleus transitions to a lower-energy state, called "Up down quark matter", or "udQM". The existence of udQM is unresolved. Theory is uncertain, and it hasn't been experimentally produced. The largest nucleus that's been produced is oganesson-294, with 118 protons and 294 nucleons. It shows no sign of udQM, so if udQM exists, it's beyond oganesson.

If udQM nuclei exist, they could potentially be long-lived. They don't fission because it would take the nucleus to a higher-energy state. They decay by alpha until they're too light to be udQM, at which point they fission.

If udQM nuclei exist, then there may exist long-lived elements from Z=140 to way beyond. These are "continental elements".

The largest nucleus that standard nuclear matter can make has Z=140. Larger nuclei fission instantly. The only way that nuclei with Z>140 can exist is if udQM exists.


Energy

Typical energies:

                              MeV        MeV/Nucleon

Chemical reaction                .000002   Varies
Beta decay                      2          Varies
Alpha decay                     6           .026
Superalpha decay               36           .16     5 or 6 alphas, in sequence. For example, Uranium-232
Superheavy decay              280           .98     Alpha, then fission. Superheavy elements with more than 108 protons
Neutron capture                 8          Varies

Fission (Helium-3)               .764       .19
Fission (Lithium-6)             4.783       .68
Fission (Beryllium-7)           1.64        .21
Fission (Boron-10)              2.34        .21
Fission (Uranium-235)         181           .77
Fission (Plutonium-239)       189           .79
Fission (Californium-252)     207           .82
Fusion of D+Li6                22.4        2.8

Beta decay, Beryllium-7          .547       .078
Beta decay, Sodium-22           2.842       .13
Beta decay, Scandium-46         2.366       .051
Beta decay, Cobalt-60           2.82        .047

High-temperature isotopes
Isotopes with a high boiling point are:

                Half life    Heat      Decay  Decay energy   Melt    Boil    Obtainable by         Formation rate
                  year      Watt/kg               MeV       Kelvin  Kelvin   neutron transmutation

Tungsten-188          .191   148700    2β            .349       3695    6203    *     .173
Iridium-192           .202                                                           *  193
Tantalum-182          .313    68866    β            1.814       3290    5731    *    6.42
Tungsten-181          .332    59200    EC           1.732       3695    6203    *          .0239
Ruthenium-106        1.023    71200    2β           3.584       2607    4423    *     .000198
Hafnium-172          1.87     11700    EC           1.835       2506    4876
Thorium-228          1.912   235000    5α+2β       34.784       2023    5061
Rhodium-101          4.07      9890    EC           1.980       2237    3968
Cobalt-60            5.27     19300    β            2.82        1768    3200    *    2.01
Osmium-194           6.02      4313    2β           2.33        3306    5285    *     .130
Platinum-193        50           17.5  EC            .057       2041    4098    *    3.81
Titanium-44         59.1       4318    EC & β+      3.798       1941    3560
Uranium-232         68.9       7545    6α          40.79        1405    4404
Iridium-192m2      241           72                                                  *   100
Thorium-229       7917           57.7  5α+3β       35.366       2023    5061
Protactinium-231 32600           16.2  6α+3β       41.33        1841    4300
Europium-152        13.5                                                                8660
Europium-154         8.59                                                                312
Europium-155         4.76                                                                312

Meitnerium-285       2.24   1020000    α+fission  220          ~3300   ~5000
Darmstadtium-293    37.7      58900    β+fission  220          ~2600   ~4700
Darmstadtium-292   133        16700    α+fission  220          ~2600   ~4700
Darmstadtium-294   380         5820    α+fission  220          ~2600   ~4700

Neutron multiplier
The isotopes that yield a large number of neutrons per fission (for thermal fission) are:

               Half life   Fission   Fission   Critical mass
                 year       barn     neutrons      kg

Fermium-257             .275 2100    5.7
Einsteinium-254         .75  2900    4.2           9.9
Californium-251      900     4801    4.1           5.46
Californium-249      351      600    4.06          6.0
Curium-245          8500     2161    3.83          9.6
Americium-242m       141     7024    3.26          9.5
Plutonium-239      14100      748    2.89         10
Uranium-235    704000000      538    2.43         52

Isotope alchemy

The transmutation options are:

                          Example                                       Means

Add a neutron             Uranium-238 → Uranium-239                     Slow neutrons from fission. Thermal neutrons at 300 Kelvin and .025 eV
Subtract a neutron        Thorium-232 → Thorium-231                     Superfast neutrons from fusion. Neutron energy = 14.1 MeV
Beta decay                Uranium-239 → Plutonium-239                   Patience
Alpha decay               Uranium-233 → Thorium-229                     Patience
Fission                   Uranium-235 → Daughter nuclei + Neutrons
Accelerator substitution  Lithium-6 + Deuteron → Beryllium-7 + Neutron
Accelerator fusion        Berkellium-249 + Calcium-48 -> Tennessine-297

Some isotopes can be made with present technology and some need future technology. Also, the more energy you have, the more isotopes you can make.

Fission reactors are the easiest way to make isotopes. They produce slow neutrons that are captured by a target nucleus and they make isotopes that are "neutron heavy", or "neutronic".

Slow neutrons tend to stick to nuclei and superfast neutrons tend to eject neutrons from nuclei. Superfast neutrons can make protonic isotopes. Superfast neutrons are produced by fusion:

Deuterium  +  Tritium  →  Helium-4 (3.5 MeV)  +  Neutron (14.1 MeV)

Most isotopes can be made with slow or superfast neutrons. Many that can't can be made with accelerator substitution. A target nucleus is bombarded with high-energy particles such as deuterons, tritons, alphas, and He-3. For example,

Lithium-6 + Deuteron + 2 MeV  →  Beryllium-7 + Neutron

Isotopes can be made by fission, for example rhodium-103 and palladium-106. Rhodium and palladium are valuable catalysts.

Isotopes can be made by spallation, where a high-energy particle blasts nucleons off a nucleus.

Isotopes can be made by fusion, where 2 nuclei are collided at the resonance energy for fusion. This is how isotopes far beyond uranium are made.

Isotopes can be made by alpha decay. For example, slow neutrons turn thorium-232 into uranium-233, and then uranium-233 alpha decays to suburanics.


Making suburanics

Slow neutrons tend to stick to nuclei and superfast neutrons tend to eject neutrons from nuclei. Superfast neutrons can make protonic isotopes. Superfast neutrons are produced by fusion:

Deuterium  +  Tritium  →  Helium-4 (3.5 MeV)  +  Neutron (14.1 MeV)

The cross sections for a fusion neutron hitting thorium-232 are (in barns):

                 Fusion neutrons   Fission neutrons   Thermal neutrons    Energy threshold
                    14.1 MeV       2.4 MeV average    .025 eV average           MeV

Capture the neutron    .0011              .096              7.299                0
Eject 1 neutron       1.786               .017              0                    6.468
Eject 2 neutrons       .522               .000072           0                   11.61
Eject 3 neutrons      0                  0                  0                   18.43
Fission                .361               .080               .000054             0
Elastic collision     2.740              4.832             14.72                 0
Inelastic collision    .468              2.690              0                     .0496
Total                 5.859              7.717             22.02

For fusion neutrons, ejection is half the cross section.


Making protonic isotopes

Protonic isotopes can be produced by bombarding a target nucleus with a high-energy particle, such as a proton, deuteron, triton, He-3, or Alpha.

Beryllium-7 can't be made with fission or fusion neutrons, but it can be made by bombarding Lithium-6 with high-energy deuterons.

Target     New    High-energy  Energy  Cross section
nucleus  nucleus   particle     MeV        barn

Li6      Be7         d            2       .2
Mg24     Na22        d            7       .2
Th232    Ac227       t           75       .5
Th232    Ra228       t          100       .0018
Th232    Th228       d           83       .272
Th232    U-232       Alpha       38       .195
Th232    Ac225       p          150       .015
Th232    Ac226       p          150       .015
Th232    Ac227       p          150       .015
Th232    Th227       p           70       .040
Th232    Th228       p           60       .085

Making suburanics with neutron subtraction

Suburanics can be made with a combination neutron addition and subtraction. Starting with thorium-232,

Th-232 → Th-231 → Th-230 → Th-229 → Th228

Th-232 → Th-233 → U-233 → U-232 → U-231 → U-230


Making suburanics with alpha decay

Radium can be made by waiting for a thorium alpha decay.

Input      Input half life    Output        Output half life
                year

Thorium-230         75380     Radium-226          1599
Thorium-232   14000000000     Radium-228             5.75
Uranium-235     704000000     Protactinium-231   32600
Uranium-238    4470000000     Thorium-230        75380

Radium generator for suburanics

Radium-226 can generate all the important suburanics with fission neutrons except for Uranium-230. The sequence is:

Radium-226  →  Actinium-227  →  Thorium-227  →  Thorium-228
→  Thorium-229  →  Thorium-230  →  Protactinium-231  →  Uranium-232

Transmutation speed

Neutron capture is slow. Some isotopes need a high neutron flux. A prime goal is maximizing neutron density, and a future civilizations will have neutron densities than today.

The neutron capture rate is:

Neutron density               = D           =   e16  neutrons/meter3           Typical for a fission reactor
Neutron speed                 = V           =  2190  meter/second              Thermal neutron at 300 Kelvin
Neutron flux                  = F = D V     =2.2e19  neutrons/meter2/second    Typical for a fission reactor
Neutron capture cross section = A           =  e-28  meter2  =  1 barn         Typical cross section
Transmutation time            = T = (DVA)-1 = 4.6e8  seconds = 14 years

Many isotopes need a small transmutation time. This can be done by increasing the neutron flux or by increasing the capture cross section. The slower the neutron, the larger the cross section.

For neutrons below 100 eV, it's often the case that "VA" is constant as a function of V.

At Oak Ridge National Laboratory, the High Flux Isotope Reactor has a flux of 2.5e19 neutrons/meter2/second.

The Oak Ridge Spallation Source produces neutron pulses with e21 neutrons/meter2/second.


Neutron sources

Neutrons are made by hitting beryllium-9 with high-energy alphas. The alpha source is often polonium-210.

Beryllium-9 + &alpha → Carbon-12 + Neutron

                   Continuous flux      Pulse flux   Continuous power
                   Neutron/meter2/s  Neutron/meter2/s     MWatt

Supernova                        -          e36                   e30 neutrons/meter3
Fission bomb                                e28
Oak Ridge fission reactor   2.5e19            -            75
Oak Ridge spallation source   3e18         2e21             1.4
ITER fusion reactor           2e18            -           500
Stellar S process              e15
Californium-252                e13
Polonium-210 + Beryllium-9     e12            -                   Polonium-210 half life = .379 years
Fusor                           e9            -                   Use high voltage to fuse D+T
Radium-226 + Beryllium-9        e8            -                   Radium-226 half life = 1599 years
Earth surface                     .0065
Deep underground               e-9

Chilled neutrons

In many cases, the slower the neutron, the higher the capture cross section.

Solid lines are scattering cross sections and dotted lines are capture cross sections.


Cryogenics
                                 Kelvin

Water melt                         273
CO2 sublime                        195
Argon boil                          87
Nitrogen boil                       77
Neon boil                           27
Hydrogen boil                       21
Helium-4 boil                        4.2
Helium-3 boil                        3.2
Helium-3 evaporative cooling          .3
Dilution refrigerator                 .002          Uses helium-3 and helium-4
Nuclear demagnetization, typical      .000001
Laser cooling, typical                .000001
Nuclear demagnetization, record low   .0000000001
Laser cooling, record low             .000000000038

Neutron wall trap

Cold neutrons bounce off walls. The critical temperature for various materials is:

          Neutron      Neutron       Neutron
        temperature  temperature      speed
            neV        Kelvin      meter/second

Nickel-58   335        .0039          8.14
Diamond     304        .0036          7.65
BeO         261        .0031          6.99
Nickel      252        .0030          6.84
Beryllium   252        .0030          6.84
Graphite    180        .0021          5.47

This is within reach of a dilution refrigerator, which can reach .002 Kelvin. It's also within reach of magnetic trapping.

An advanced civilization will have unlimited helium-3 and can make a large dilution refrigerator. It can make a neutron wall trap that can collect all the outgoing neutrons from a fission reactor and funnel them to a focus. The only limit on neutron density is neutron degeneracy, which is 1022 neutrons/meter3 at .003 Kelvin.


Neutron magnetic trap

Ultracold neutrons can be trapped magnetically. Neutrons have a magnetic moment of 50 neV/Tesla. For a 3 Tesla field, this is the same temperature range as a dilution refrigerator and as for wall trapping.

                                            Magnetic fied (Tesla)

Neodymium magnet                                     1.25
Magnetic resonance imaging                           7
Superconducting magnet max, continuous operation    32
Resistive magnet max, continuous operation          38
Pulsed magnet max, non-destructive                 100
Pulsed magnet max, destructive                    2000

White dwarf                                       1000
Neutron star                                  10000000
Magnetar                                   10000000000
Magnetar max                              100000000000

Neutron density

Neutron density is limited by degenercy pressure. For neutrons,

Type         Energy        Temperature   Wavelength     Speed       Degenerate density
               eV            Kelvin      Angstroms   Meter/second   #/meter3

Fusion    14100000                         .000061    51900000
Fast       2000000                         .00016     19600000
Thermal           .0253       294          1.45           2200      3.3⋅1029
Cold              .00036        4.2       12.1             263      5.6⋅1026
Ultracold         .00000022      .0025   497                 6.4    8.1⋅1021

Fast neutrons are from fission.

Fusion neutrons are from the fusion of D+T->He4+n, which produces a 14.1 MeV neutron.


Hurdles

Some isotopes have hurdles to their formation. For example, osmium-194 is formed by adding neutrons to osmium-192, and the hurdle is that osmium-193 has a short half life of 1.25 days. There's limited time for osmium-193 to capture a neutron. Fortunately, the capture cross section of osmium-193 is high.

              Half life    Neutron capture (barns)

Osmium-192       Stable           3.12           Input isotope
Osmium-193      1.25 days        38.0            Hurdle isotope
Osmium-194      6.0 years          .043          Output isotope

If there is a hurdle isotope, the formation rate of the output isotope is proportional to:

Hurdle half life                     = T
Hurdle neutron capture cross section = σc
Hurdle fission cross section         = σf
Natural fraction                     = F             Fraction of the natural element that can transform to the output isotope
Capture fraction                     = C = σc/(σcf)
Formation rate of output isotope     = Q = T σc F C

This is for the case of an output isotope with a long half life and a hurdle isotope with a short half life.

If the output isotope has a short half life, then the output isotope is the hurdle. "T" becomes the half life of the output isotope and σc becomes the capture cross section for the isotope preceeding the output isotope.

If the hurdle time is more than 1 year, we use a time of 1 year.

In the plot, "Island #1 and #2" are the nuclear islands of stability. Island #1 needs a formation time of order .1 seconds, and island #2 needs .01 seconds, and superheavy isotopes (udQM regime) need .001 seconds.

The isotopes with hurdles to their formation are:

Output        Output     Hurdle   Capture  Natural   Capture   Production   Hurdle
             Half life  half life                                 rate
               year       year     barn    fraction  fraction  barn*year

Europium-152     13.5   13.5     9100         .952   1       8660          Europium-151
Europium-154      8.59   8.59     312        1       1        312          Europium-153
Europium-155      4.76   4.76     312        1       1        312          Europium-153
Iridium-192        .202   .202    954        1       1        193          Iridium-192
Iridium-192m2   241    241        100        1       1        100          Iridium-192m2
Tritium          12.3    Stable   940         .0759  1         71          Lithium-6
Thulium-170        .352    .352   105.6      1       1         37.2        Thulium-170
Thulium-171       1.91     .352    87.6      1       1         30.8        Thulium-170
Caesium-134       2.06   2.06      30.3      1       1         30.3        Caesium-137
Americium-242m  141    141         84        1        .10       8.4        Americium-242m
Tantalum-182       .313   .313     20.5      1       1          6.42       Tantalum-182
Platinum-193     50      Stable    10.0       .381   1          3.81       Platinum-192
Cobalt-60         5.27   5.27       2.007    1       1          2.007      Cobalt-60
Carbon-14      5730      Stable     1.931     .996   1          1.92       Nitrogen-14
Plutonium-238    87.7   2144000   171         .0072   .146      1.23       Neptunium-237
Argon-39        269      Stable      .8      1       1           .8        Argon-38
Cadmium-109       1.26   Stable     1.1       .518   1           .57       Cadmium-108
Scandium-46        .229   .229      2.366    1       1           .542      Scandium-46
Iron-55           2.737  2.737      2.25      .0585  1           .36       Iron-55
Deuterium       Stable   Stable      .333     .99985 1           .333      Proton
Zinc-65            .667   .667       .93      .492   1           .305      Zinc-65
Tungsten-188       .191   .00270   64.1      1       1           .173      Tungsten-187
Californium-252   2.64   2.64       2.49     1        .0673      .168      Curium-248
Osmium-194        6.0     .00343   38.04     1       1           .130      Osmium-193
Technetium-99 211000   211000        .132     .903   1           .119      Technetium-99
Strontium-90     28.9     .138       .420    1       1           .0580     Strontium-89
Tungsten-181       .332   .332     60         .0012  1           .0239     Tungsten-181
Promethium-145   17.7     .931       .7       .0308  1           .022      Samarium-145
Samarium-145       .931   .931       .7       .0308  1           .022      Samarium-145
Californium-254    .166   .049     20.0      1        .0151      .0148     Californium-253  1303
Polonium-210       .379   .379       .0338   1       1           .0128     Polonium-210
Iodine-131         .0220 Stable      .29      .341   1           .00218    Tellurium-130
Ruthenium-106     1.023   .000507    .390    1       1           .000198   Ruthenium-105
Argon-42         32.9     .000208    .509    1       1           .000106   Argon-41
Silicon-32      153       .000299    .107    1       1           .000032   Silicon-31
Curium-250     8300       .000122   1.60     1        .138       .0000027  Curium-249         10
Lead-210         22.3     .000371    .00143  1       1           .00000053 Lead-209
Caesium-137      30.2     .0360  Unknown     1       1                     Caesium-136

Output        Output     Hurdle   Capture  Natural   Capture   Production   Hurdle
             Half life  half life                                 rate
               year       year     barn    fraction  fraction  barn*year
Einsteinium-257    .0211  .000048    Unknown                  Unknown      Einsteinium-256
Einsteinium-259    .0180  .000074    Unknown                  Unknown      Einsteinium-258
Fermium-257        .275   .000300    Unknown                  Unknown      Fermium-256

Cooking europium

Subjecting natural europium to neutrons for a short time produces mostly europium-152.

Subjecting natural europium to neutrons for a medium time produces mostly europium-154.

Subjecting natural europium to neutrons for a long time produces 2/3 europium-154 and 1/3 europium-155.

          Half life   Neutron capture  Natural   Energy   Gamma max   Decay
            year           barn        fraction   MeV       MeV

Europium-151    Stable      9100        .478    -         -
Europium-152     13.5      11800       0       1.86      1.408
Europium-153    Stable       312        .522    -         -
Europium-154      8.59      1663       0       1.968     1.274
Europium-155      4.76      3843       0        .252      .147
Europium-156       .0416     100       0
Europium-157       .00174              0

Thulium-169     Stable       105.6     1        -
Thulium-170        .352       87.6     0                  .968     β
Thulium-171       1.91         9.90    0                  .096     β

Promethium-143     .725        3.07    0                           β+
Promethium-144     .994       15.09    0                           β+
Promethium-145   17.7          5.28    0        .164      .072     EC
Promethium-146    5.53         8.41    0       1.495     1.189     EC
Promethium-147    2.623      167.2     0        .224      .224     Β     72 barn to Pm-148m.    82 barns to Pm-148
Promethium-148     .0147               0                           β
Promethium-148m    .113                0                           β

Neodymium-142   Stable        18.7      .272
Neodymium-143   Stable       337        .112
Neodymium-144   Stable         3.6      .238
Neodymium-145   Stable        42        .0829
Neodymium-146   Stable         1.4      .172
Neodymium-147      .0301     142.9     0                           β
Neodymium-148   Stable                  .0575
Neodymium-149      .000194             0                           β
Neodymium-150   Stable                  .0563

Samarium-144    Stable          .7      .0308
Samarium-145       .931      280.3     0        .617      .061     EC
Samarium-146  68000000          .382   0
Samarium-147    Stable        57        .150
Samarium-148    Stable        24        .112
Samarium-149    Stable     42080        .138
Samarium-150    Stable       104        .0737
Samarium-151     90        14070       0
Samarium-152    Stable       206        .267
Samarium-153       .00528              0
Samarium-154    Stable         8.4      .227

Making transuranics

Making transuranics takes many neutrons. Also, fission can halt the process. When going from uranium-238 to californium-251, the fraction of isotopes that make it to californium-251 is .0000151.

There are no hurdles with short half lives until fermium-258, with a half life of .000370 seconds.

The sequence for making transuranics is:

              Half life      Fission    Capture  Capture  Cumulative     Decay
                year          barn       barn    fraction  fraction

Uranium-238  4470000000            .000010    2.68  1        1           α
Plutonium-239     14100         748        1017      .58      .58        α
Plutonium-240      6561            .030     290     1         .58        α
Plutonium-241        14.3       937         363      .28      .16        β
Plutonium-242    373000            .0026     18.5   1         .16        α
Americium-243      7370            .2        75.3   1         .16        α
Curium-244           18.1         1.1        13      .92      .16        α
Curium-245         8500        2161         383      .151     .147       α
Curium-246         4730            .17        1.36   .89      .0222      α
Curium-247     15700000          82          58      .41      .0198      α
Curium-248       340000            .34        2.49   .88      .00811     α
Californium-249     351        1666         483      .22      .00714     α
Californium-250      13.08      112        1701      .94      .00157     α
Californium-251     900        4894        2849      .37      .00148     α
Californium-252       2.64       33.0        20.4    .38      .000546    α
Californium-253        .049    1303          19.95   .0151               β
Californium-254        .166       2.001       4.51   .69                 Fission
Einsteinium-255        .109        .503      55.4   1                    β
Fermium-256            .000300  Unknown   Unknown   Unknown              α
Fermium-257            .275    2951           3.003  .00102              α
Fermium-258            .000370  Unknown   Unknown   Unknown              Fission
Fermium-259           1.5       Unknown   Unknown   Unknown              Fission
Fermium-260            .004     Unknown   Unknown   Unknown              Fission

A neutron could either be captured or it could trigger fission. "Capture fraction" is the fraction of capture events.

"Cumulative fraction' is the product of capture fractions up to the given isotope.


Price of neutrons

Energy per neutron    = E       =       200  MeV/neutron
Neutron mass          = M       =  1.67e-27  kg
Neutron energy/mass   = e = E/M =    1.9e16  Joule/kg
Electricity energy/$  = L       =        30  MJoule/$
Neutron price/kg      = P = e/L =       640  M$/kg

Price of actinides

A neutron can turn uranium-238 into plutonium-239. The energy cost of plutonium-239 is 2.7 M$/kg.

Actinides beyond plutonium take many neutrons to make. It takes 14 neutrons to get from uranium-238 to californium-252.


Calutron

A calutron separate isotopes with a magnetic field.


Isotope prices and production

Protons              Price/kg       World produce   America stockpile   Natural fraction
                      M$/kg           kg/year            kg

  1  Hydrogen-2               .004       1000000                          .00015
  1  Hydrogen-3             30                10          30             0
  2  Helium-3                1                10          30              .000002
  2  Helium                   .000024   50000000
  3  Lithium                  .000070   36000000
  3  Lithium-6                .06                                         .0759
  4  Beryllium                .00150      425000                                   All beryllium-9
  4  Beryllium-7                                                         0
  5  Boron-10                                                             .20
  6  Carbon-12                .12                                         .989
  6  Carbon-14                                                            .000000000001
 21  Scandium-46
 27  Cobalt-60
 38  Strontium-90             .01
 55  Caesium-137
 63  Europium-152
 63  Europium-154
 77  Iridium-192
 77  Iridium-192m
 84  Polonium-209     50000000
 84  Polonium-210
 88  Radium-226               .1               0          30
 88  Radium-228               .1               0          30
 89  Actinium-227            1
 90  Thorium                  .000290   10000000
 90  Thorium-228
 90  Thorium-229
 90  Thorium-230
 90  Thorium-231
 91  Protactinium-231         .28
 92  Uranium                  .000101   70000000
 92  Uranium-230
 92  Uranium-232
 92  Uranium-233                                        2000
 92  Uranium-235              .1                      480000              .0072
 93  Neptunium-237            .66
 94  Plutonium-238
 94  Plutonium-239           6.5                       80000
 95  Americium-141            .7                          10
 95  Americium-142m
 95  Americium-143            .7                          10
 95  Curium-242                                1          10
 95  Curium-243
 95  Curium-244            185                  .17       10
 95  Curium-245
 95  Curium-246
 95  Curium-247                                             .1
 95  Curium-248         160000                  .0001
 96  Curium-250
 97  Berkelium-249      185000                  .020     N/A
 98  Californium-249    185000                  .0005
 98  Californium-250
 98  Californium-251
 98  Californium-252     60000                  .5       N/A
 99  Einsteinium-253                            .01      N/A
 99  Einsteinium-254                            .000001  N/A
100  Fermium-257

Power

                              Power       Power        Distance
                              Watts       Sun=1       light year

Human civilization, 1800      6.0e11
Human civilization, 1900      1.3e12
Human civilization, 2023      2.0e13
Solar power hitting Earth     1.7e17
Sun                           3.8e26             1            0
Star Sirius                   9.7e27            25.4          8.6
Star Aldebaran                2.0e29           520           65
Star Spica                    7.8e30         20500          280
Star Naos                     3.1e32        813000         1080
Star eta Carine               1.7e33       4600000         7500
Milky Way central region      1  e35                      26000   Stars within 10 light years of the center
Galacy Centaurus A AGN                                 11000000   Nearest active galactic nucleus
Milky Way total               5  e36                          -
Virgo central galaxy          5  e37                   53500000
Quasar Markarian 231          1.4e39                  581000000   Nearest quasar
Quasar Ton 618                4  e40                18200000000   Brightest quasar
Galaxy W2246-0526             1.3e41                12600000000   Brightest galaxy

Exotic isotopes

Pure alpha isotopes

Isotopes that decay by alpha and don't produce betas or gammas have value because they can be around humans. The pure alpha isotopes are:


                 Half life   Power/Mass   Obtainable by
                   year       Watt/kg     neutron transmutation

Fermium-257           .275                     *        Fm257 -> Es253 -> Bk249
Polonium-210          .379   144000            *
Curium-242            .446   124000
Polonium-208         2.898
Curium-244          18.1       2823            *        Cm242 -> Pu240 -> U236
Curium-243          29.1       1885            *        Cm243 -> Pu239 -> U235
Gadolinium-148      75          800
Plutonium-238       87.7        578            *
Polonium-209       125.2                                Po209 -> Pb205 -> Tl205   The electron capture has a half life of 15 Myr
Americium-241      432          114            *

Low neutron capture cross section

A nuclear reactor needs materials with a low neutron capture cross section. Zirconium is the favored structural metal.

         Neutron capture   Natural    Neutron       Density    Atom      Stopping
                           fraction   scatter                 density    power
             barn                      barn          g/cm3

Oxygen            .00028          -
Carbon            .0035           -
Helium            .007            -
Beryllium         .0092           -
Bismuth           .034            -
Neon              .04             -
Magnesium         .063            -
Lead              .171            -
Zirconium         .184            -
Aluminum          .232            -
Hydrogen          .332            -
Niobium          1.15             -
Ruthenium        2.56             -
Molybdenum       2.6              -
Nickel           4.49             -
Platinum        10                -
Osmium          15                -
Tungsten        18.3              -
Tantalum        20.6              -
Hafnium        104                -

Hydrogen-3       0                0           2.178
Helium-4         0                1.000        .961     .145   .036      .036
Carbon-14         .000000310      0           3.152    4.11    .294      .93
Nitrogen-15       .000024          .004       5.293
Beryllium-10      .000100         0           6.291    2.06    .206     1.30
Oxygen-18         .000141          .00205     3.987
Oxygen-16         .000190          .998       4.498
Lead-208          .000230          .524      12.94    11.34    .055      .72
Hydrogen-2        .000550          .000145    4.705
Carbon-13         .00137           .011 
Carbon-12         .00389           .989
Boron-11          .00508           .80
Beryllium-9       .0076           1                    1.85
Zirconium-90      .0107            .514
Magnesium-26      .0382            .110
Lithium-7         .0454
Molybdenum-92     .0614            .146
Ruthenium-106     .146            0
Titanium-50       .179             .0518
Aluminum-27       .231            1
Oxygen-17         .244
Hydrogen-1        .333             .9999     32.81
Chromium-54       .36              .0236
Platinum-196      .72              .253
Iron-58          1.28              .0028
Nickel-64        1.52              .00926
Osmium-192       3.12              .41
Tungsten-183    10.1               .143
Hafnium-180     12.92              .351
Tantalum-181    20.5               .999

Neutron shield
High neutron capture cross section

The best isotope for neutron shielding is gadolinium-157, with a neutron capture cross section of 259000 barns. Natural gadolinium is a mix of isotopes with an overall cross section of 49000 barns.

Elements and isotopes with a high neutron capture cross section are:

          Neutron capture  Price/kg  Quality
              barns          $/kg    barns/$

Gadolinium       49000       29     2450
Samarium          5922       13.6    740
Europium          4600      287       15
Cadmium           2450        2.7   1220
Boron              767        3.7    183
Lithium             70.5     70         .35

Xenon-135      2650000                         Half life = .00104 year
Zirconium-88    861000                         Half life = .228 year
Gadolinium-157  259000
Gadolinium-155   61100
Beryllium-7      56800
Samarium-149     42080
Cadmium-113      30000
Europium-151      9100
Helium-3          5333
Boron-10          3835
Lithium-6          940

Neutron source

Neutrons can be generated by bombarding beryllium-9 with alpha particles.

α + Beryllium-9  → Carbon-12 + Neutron

Gamma source

             Half life   Decay   Gamma energy   Obtainable by neutron transmutation
               year                  MeV

Antimony-124      .165   Beta       2.09                Most gammas are 1.69 MeV. Max 2.09 MeV
Cobalt-60        5.26    Beta       1.33        *
Sodium-22        2.6     Beta+      1.28
Hafnium-178m    31       Gamma       .507       *

Tritium source
Lithium-6 + Neutron  →  Helium-4 + Tritium           Cross section of 940 barns

Medical isotopes

               Half life   Obtainable by
                 year      neutron transmutation

Fluorine-18       .000209
Molybdenum-99     .00752     *      Decays to Technetium-99m, which has a half life of 6.01 hours
Thallium-201      .00832
Iodine-131        .022       *
Iodine-125        .0362
Palladium-103     .0465      *
Strontium-82      .0694             Decays to Rubidium-82
Iridium-192       .202       *
Strontium-89                 *
Samarium-153                 *
Rhenium-186                  *
Lutetium-177                 *
Bismuth-213                  *
Lead-212                     *
Radium-223
Boron-10         Stable    Natural
Gadolinium-157   Stable    Natural

Chain decays
Nuclei exist that decay twice or more. For example, osmium-194 decays to iridium-194 and then to platinum-194.

Some isotopes undergo 5 or 6 alpha decays, such as uranium-232. This is the red line in the plot.

U-232 → Th-228 → Ra-224 → Rn-220 → Po-216 → Pb-212 → Bi-212 → Po-212 → Pb-208

The double-decay nuclei with half lives between 1 month and 100 years are:

                                       1st decay  2nd decay  Total    1st     2nd   Obtainable by neutron transmutation
                                       half life  half life  energy  energy  energy
                                         year       year      MeV     MeV     MeV

Osmium-194    → Ir-194 → Pt-194   6.02     .00022   2.330   .096   2.234  *
Tungsten-188  → Re-188 → Os-188    .191    .00194   2.469   .349   2.120  *
Rhenium-184m  → Re-184 → Os-184    .463    .104     .646    .188    .458  *
Hafnium-172   → Lu-172 → Yb-172   1.87     .0283    1.835   .338   1.497
Fermium-247   → Es-253 → Cm-249    .275    .0560                          *
Rhodium-102m  → Rh-102 → Ru-102   3.742    .567     1.509   .141   1.268
Einstein-254  → Cf-250 → Cm-246    .755  13.3                             *
Titanium-44   → Sc-44  → Ca-44   59.1      .00046   3.798   .146   3.652
Strontium-90  → Y-90   → Zr-90   28.9      .00731   2.826   .546   2.280  *
Iridium-192m  → Ir-192 → Pt-192 241        .202     1.615   .155   1.460  *
Tin-121m      → Sn-121 → Sb-121  43.9      .00308    .396   .0063  .390   *
Argon-42      → K-42   → Ca-42   32.9      .00141   4.124   .599   3.525  *
Silicon-32    → P-32   → S-32   153        .0391    1.919   .21    1.709  *
Germanium-68  → Ga-68  → Zn-68     .742    .000129

High boiling point
The elements with a boiling point larger than 3950 Kelvin are:

              Melt    Boil   Density

Zirconium      2128   4650
Niobium        2750   5017
Molybdenum     2896   4912
Technetium     2430   4538
Ruthenium      2607   4423
Rhodium        2237   3968
Lutetium       1925   3675
Hafnium        2506   4876   13.3
Tantalum       3290   5731   16.7
Tungsten       3695   6203   19.2
Rhenium        3459   5309   21.0
Osmium         3306   5285   22.6
Iridium        2719   4403   22.6
Platinum       2041   4098   21.4
Thorium        2023   5061
Protactinium   1810   4300
Uranium        1405   4404   19.1
Neptunium       912   4447

Curium-240

Curium-240 produces 2 alphas with short half lives and becomes Uranium-232, which has a long half life. Uranium-232 produces an alpha with a long half life and then 5 more alphas with short half lives. It can be used as an alpha rocket, where the first two decays give it a fast launch, and the remaining decays power it for a long time. The decay sequence of Curium-240 is:

              Half life
                year

Curium-240       .0739       Alpha
Plutonium-236   2.858        Alpha
Uranium-232    68.9          Alpha
Thorium-228     1.912        Alpha
Radium-224       .00986      Alpha
Radon-220        .0000018    Alpha
Polonium-216     .000000005  Alpha
Lead-212         .00121      Alpha
Bismuth-212      .00012      Beta
Tellurium-208    .0000057    Alpha
Lead-208       Stable        Beta

Neutron cross sections

Cross sections for fusion neutrons at 14.1 MeV, in millibarns. All columns are fusion neutrons except the last column, which is fast fission neutrons. For fusion neutrons, the usual outcome is for neutrons to be subtracted from the target nucleus.

Thorium is more likely to lose neutrons than uranium.

           (n,2n)  (n,3n)  (n,fission)  (n,inelastic)  (n,G)    (n,2n)
                                                                fission


Actinium-227  2170   353            62.8     445        1.119    15.87
Thorium-228   1897    85.8         598       498        1.23      7.39
Thorium-229   1717    92.7         864       346        1.19     33.5
Thorium-230   1856   244           564       424         .96     12.2
Thorium-231   1685   336           658       349        1.21     42.7
Thorium-232   1786   522           361       468        1.14     16.8
Uranium-320    174      .0126     2518       416         .78       .138
Uranium-321     75      .000028   2474       403         .69      2.08
Uranium-322    401      .77       2570       420         .82       .760
Uranium-233    181      .271         1.84    368         .58      1.84
Curium-242     231      .120      2907       359        1.19       .921

Fission energy

The prompt kinetic energy released by fission is:

         Fission energy (MeV)

Actinium        168
Thorium         172
Protactinium    177
Uranium         181
Neptunium       185
Plutonium       189
Americium       195
Curium          198
Berkelium       203
Californium     207

Nuclear island of stability

There is a hypothetical "island of stability" around atomic number 112 where nuclei may be long-term stable. A second island may exist at atomic number 126.

Experiments can only measure the longest-lived isotope up to a proton number of 105, and beyond that we plot theory. Theoretical half lives are uncertain by an order of magnitude.

It's possible that for large nucleon number, larger than around 300, that the nucleus transitions to a lower-energy state, called "Up down quark matter", or "udQM". The existence of udQM is unresolved. Theory is uncertain, and it hasn't been experimentally produced. The largest nucleus that's been produced is oganesson-294, with 118 protons and 294 nucleons. It shows no sign of udQM, so if udQM exists, it's beyond oganesson.

If udQM nuclei exist, they could potentially be long-term stable. They don't fission because it would take the nucleus to a higher-energy state. They decay by alpha until they're too light to be udQM, at which point they fission.

If udQM nuclei exist, then there may exist long-lived elements from Z=140 to way beyond. These are "continental elements".

The largest nucleus that standard nuclei can make has Z=140. Nuclei larger fission instantly. The only way that nuclei with Z>140 can exist is if udQM exists.

In the isotope table, we use experimental data from Wikipedia if it exists, otherwise we use theory from https://wwwndc.jaea.go.jp/CN14 and https://t2.lanl.gov/nis/data/astro. Nobel gases have a closed shell of electrons, and the shell numbers are called "magic numbers". The magic numbers for electron shells are:

Helium       2
Neon        10
Argon       18
Krypton     36
Xenon       54
Radon       86
Oganesson  118

The magic numbers for neutrons are 2, 8, 20, 28, 50, 82, 126, 184. The magic numbers for protons are the same as for neutrons, up to 82, and the next proton magic numbers are 114, 126, 154, and 164. Nuclei that are magic for both protons and neutrons are:

             Protons  Neutrons

Helium-4          2      2
Oxygen-16         8      8
Calcium-40       20     20
Calcium-48       20     28
Lead-208         82    126
Flevorium-298   114    184   Undiscovered
Unnamed         126    216   Undiscovered
Unnamed         126    228   Undiscovered
Unnamed         154    308   Undiscovered
Unnamed         164    308   Undiscovered
Unnamed         164    318   Undiscovered
Unnamed         164    406   Undiscovered

The nuclei from helium-4 to lead-208 are stable.


Fermi gas

A Fermi gas with a Fermi energy of 335 neV has a density of 1.39e23 particles/meter3

Fermi number density     =  n = 16π/3 λ-3=      1.39e23  particles/meter3
Fermi wavelength         =  λ            =      4.94e-8  meter
Fermi momentum           =  Q            =     1.34e-26  kg*meter/second
Planck constant          =  h =  Q ℏ     =    6.626e-34  Joule*second
Fermi energy             =  E =  Q2/(2m) =  ℏ2/(2m) (3π2n)2/3
                                         =          335  neV
Neutron mass             =  m            =    1.675e-27  kg

Isotope charts


Radioisotopes

Full list.

                Half life    Heat     Decay  Electron  Elect  Gamma  Form rate  Obtainable    Decay
                                               max      ave    max              by neutron
                  year      Watt/kg    MeV     MeV      MeV    MeV   barn*year  transmute

Neutron               .000027            .782   .782                              *  β          Half life = 879 seconds
Einsteinium-253       .0560                                                       *  α
Tungsten-188          .191    19920      .349                            8.49     *  2β
Californium-254       .166 11200000   207                                 .0102   *  Fission
Iridium-192           .202    77147     1.460                          134        *  β
Scandium-46           .229   460000     2.366   .357  .112  1.121         .38     *  β
Sulfur-35             .239                      .167  .0488                       *  β
Fermium-247           .275                                                        *  α
Tantalum-182          .313    65260     1.814                            4.45     *  β
Tungsten-181          .332    59100     1.732                             .0166   *  EC
Thulium-170           .352    11800      .968   .968         .968       37.2      *  β    M    73% e- .968 MeV. 22% e- .884 MeV & .084 MeV gamma
Polonium-210          .379   139000     5.41   0                          .0089   *  α   M
Calcium-45            .445               .257   .257         .257                 *  β
Curium-242            .446                                                        *  α
Gadolinium-153        .658               .484                .173                 *  EC
Zinc-65               .668    63900     1.352                             .21     *  β+
Einsteinium-254       .755                                                        *  α
Samarium-145          .931                                                        *  EC
Ruthenium-106        1.023    67700     3.584                             .00014  *  2β
Cadmium-109          1.267                                                        *  EC
Thulium-171          1.91                .0965                          30.8      *  β
Caesium-134          2.06     15300     2.059                           21        *  β
Promethium-147       2.6       1200      .224                             .86     *  β
Californium-252      2.64     41400    12.33   0                                  *  α 96.9% (6.12 Mev). Fission 3.09% (207 MeV)
Iron-55              2.74      3140      .231                             .091    *  EC
Thallium-204         3.78                .766                                     *  β
Europium-155         4.76       705      .252                                     *  β
Cobalt-60            5.27     18300     2.82                             1.39     *  β
Promethium-146       5.5                1.495                                     *  EC 66%, e- 34%
Osmium-194           6.02      4313     2.330                             .090    *  2β
Europium-154         8.59      3049     1.968                          216        *  β
Barium-133          10.51       758      .517                             .0049   *  EC
Tritium             12.33      1031      .0186  .0186 .0057             49        *  β
Europium-152        13.5       1858     1.86                          6005        *  β & EC
Californium-250     13.08                                                         *  α
Cadmium-113m        14.1        340      .264                                     *  β
Plutonium-241       14.3       3050     4.90                                      *  β
Promethium-145      17.7        131      .164                                     *  EC
Curium-244          18.1                                                          *  α
Lead-210            22.3       2907     9.100  0                          .00000037 * α
Strontium-90        28.9        460     2.826                             .29     *  β, β    M
Curium-243          29.1
Caesium-137         30.1        583     1.176                                     *  β
Hafnium-178m2       31          930     2.446                                     *  γ
Argon-42            32.9                 .599                                     *  β
Tin-121m            43.9        153      .396                             .088    *  IT, β
Platinum-193        50           17.5    .057                            6.93     *  EC
Plutonium-238       87.7        578     5.59   0                          .125    *  α
Samarium-151        90.0         11.6    .077                           34        *  β
Nickel-63          100.1          5.52   .066   .066  .017   .066        9.96     *  β
Americium-242m     141          725    12.33   0                         5.8      *  2α
Silicon-32         153          804     1.92                             2.22     *  β, β
Iridium-192m2      241           72     1.628                           69        *  β
Argon-39           269                   .566                                     *  β
Californium-249    351                                                            *  α
Americium-241      432.2        114                                               *  α     M
Californium-251    900                                                            *  α
Curium-246        4760                                                            *  α
Carbon-14         5730            3.99   .156   .156  .049                        *  β
Plutonium-240     6561                  5.256                                     *  α
Americium-243     7370                                                            *  α+β
Curium-250        8300          170   148                                 .000019 *  Fission 74%, Alpha 18%, Beta 8%
Curium-245        8500                                                            *  2α+β
Plutonium-239    24110                                                            *  α
Technetium-99   211000             .003  .294                                     *  β
Curium-248      348000                                                            *  α
Plutonium-242   375000                                                            *  α
Beryllium-10   1390000                   .556                                     *  β
Technetium-97  4200000                                                            *  EC
Technetium-98  4200000                                                            *  β
Curium-247    15600000                                                            *  3α+2β
Uranium-236   23420000                                                            *  α
Plutonium-244 81300000                                                            *  3α+2β

Thorium-227           .0512 9194000    36.14                                         5α+2β
Uranium-230           .0554 9280000                                                  6α+2β
Thorium-228          1.912   235000    34.784                                        5α+2β
Radium-228           5.75     90660    40.198                                        5α+4β
Actinium-227        21.8      21600    36.18                                         5α+3β
Uranium-232         68.9       7545    40.79                                         6α+2β
Radium-226        1599          286    34.958                                        5α+4β
Thorium-229       7917           57.7  35.366                                        5α+3β
Protactinium-231 32600           16.2  41.33                                         6α+3β
Thorium-230      75380            6.78 39.728                                        6α+4β
Uranium-233     159200                                                            *  6α+2β
Uranium-234     245500                                                               7α+4β
Neptunium-237  2144000                                                               8α+4β
Curium-247    15600000                                                            *  3α+2β
Uranium-235  703800000                                                            *  7α+4β
Uranium-238 4468000000          .00010 51.771                                     *  8α+6β
Thorium-232 14050000000                47.655                                     *  6α+2β

Mendelevium-260       .076                                                           Fission
Mendelevium-258       .141                                                           α
Beryllium-7           .146  1822000      .547                                        EC
Cobalt-56             .212                                                           β+
Rhenium-184m          .463    16000                                                  IT, β
Thulium-168           .255                                                           β+
Gold-195              .510               .227                .210                    EC
Cobalt-57             .744               .836                .137                    EC
Manganese-54          .855    64400                                                  EC
Vanadium-49           .901               .602                                        EC
Californium-248       .913                                                           α
Einsteinium-252      1.29                      0                                     α, EC
Lutetium-173         1.37                                    .630                    EC
Tantalum-179         1.82               1.060                                        EC
Plutonium-236        2.858                                                           α
Hafnium-172          1.87     11700     1.835                                        EC
Sodium-22            2.6      68700     2.842                                        β+ or EC
Polonium-208         2.99                      0                                     α
Rhodium-101          3.3                                                             EC
Lutetium-174         3.31                                                            β+
Rhodium-102m         3.742                                                           β+
Rhodium-101          4.07      9890     1.980                                        EC
Niobium-93m         16.1                                                             IT
Bismuth-207         31.55               2.397                                        β+
Europium-150        36.9                2.259                                        β+
Titanium-44         59.1       4318     3.798                                        EC, β+
Terbium-157         71.0         11.0    .060                                        β+
Gadolinium-148      75          800            0                                     α
Polonium-209       125.2                       0                                     α
Terbium-158        180                                                               β+
Iridium-192m2      241                                                               IT, β
Holmium-163       4570                                                               EC

Darmstadtium-293    37.7      58900   220                                            β+fission   Theoretical
Darmstadtium-292   133        16700   220                                            α+fission  Theoretical
Copernicium-294    355         6230   220                                            α+fission  Theoretical
Darmstadtium-294   380         5820   220                                            α+fission  Theoretical

Argon-37          .0824                  .814  0                                  *  EC
Argon-39       269                                                                *  β
Argon-42        32.9                                                              *  β
Krypton-85      10.78                                                             *  β
Xenon-127         .0994                  .662  0             .618                 *  EC

                Half life    Heat     Decay  Electron  Elect  Gamma  Form rate  Obtainable    Decay
                                               max      ave    max              by neutron
                  year      Watt/kg    MeV     MeV      MeV    MeV   barn*year  transmute

A neutron has a half life of 610.1 seconds and a decay energy of .782 MeV.


Radioisotopes with low-energy X-rays

Full list.

          Half life   Power/mass   Decay   Gamma    Formation   Obtainable by   Decay
                                   energy   max       rate      neutron
            year       Watt/kg      MeV     MeV     barn*year   transmutation

Nickel-63      100.1        5.52   .017   .017       2.5           *           β
Tritium         12.33     315      .0186  .0186     71             *           β
Rubidium-83       .236             .910   .0322      0                         EC
Arsenic-73        .220             .341   .0534      0                         EC
Terbium-157     71.0       11.0    .060   .054       0                         EC
Samarium-145      .931             .617   .061        .022         *           EC
Tantalum-179     1.82              .110   .065       0                         EC
Promethium-145  17.7      131      .164   .072        .022         *           EC
Samarium-151    90.0       11.6    .077   .077                     *           β
Platinum-193    50         17.5    .057   .076       3.81          *           EC
Cadmium-109      1.26              .216   .088        .57          *           EC
Thulium-171      1.91     606      .096   .096      30.8           *           β
Gadolinium-153    .658             .484   .100                     *           EC
Iron-55          2.74    3140      .231   .126        .36          *           EC
Cobalt-57         .744             .836   .136       0                         EC
Europium-155     4.76     705      .252   .147     312             *           β
Cerium-139        .377             .278   .166                     *           EC
Gadolinium-153    .658             .484   .173                     *           EC
Gold-195          .510             .227   .210                                 EC
Promethium-147   2.6     1200      .224   .224       1.3           *           β
Calcium-45        .445             .257   .257                     *           β
Rhodium-101      3.3     9890      .541   .325       0                         EC 
Europium-149      .255             .692   .328       0                         EC
Barium-133      10.51     758      .517   .384                              *           EC
Tin-121m        43.9      153      .396   .390        .01          *           IT & β
Beryllium-7       .146             .862   .478       0                         EC

Vanadium-49       .901    232      .602   ?          0                         EC

Making uranium from bismuth

Making radium from polonium needs extreme neutron flux. The hurdle is polonium-212 with a half life of 249 nanoseconds. Once you have radium, it's easy to get to thorium.

                    Half life   Neutron capture   Decay
                     second          barn

Bismuth    209    Stable             .0338
Bismuth    210    433000                          e-
Bismuth    211       130                          alpha
Polonium   210  12000000             .00123       alpha
Polonium   211          .516                      alpha
Polonium   212          .000000249                alpha
Polonium   213          .00000365                 alpha
Polonium   214          .000164                   alpha
Polonium   215          .00178                    alpha
Polonium   216          .145                      alpha
Polonium   217         1.47                       alpha 95%, beta 5%
Polonium   218       186                          alpha
Polonium   219       618                          beta 71.8%, alpha 28.2%
Polonium   220        40                          beta
Polonium   221       132                          beta
Polonium   222       546                          beta
Polonium   223         6                          beta
Polonium   224       180                          beta
Polonium   225        10                          beta
Polonium   226        60                          beta
Polonium   227         2                          beta
Astatine   217          .0323                     alpha
Astatine   218         1.27                       alpha
Astatine   219        56                          alpha 97%, beta 3%
Astatine   220       223                          beta 92%, alpha 8%
Astatine   221       138                          beta
Astatine   222        54                          beta
Astatine   223        50                          beta
Astatine   224       150                          beta
Astatine   225         3                          beta
Astatine   226       420                          beta
Astatine   227         5                          beta
Astatine   228        60                          beta
Astatine   229         1                          beta
Radon      225       280                          beta
Radon      226       444                          beta
Radon      227        20.8                        beta
Radon      228        65                          beta
Radon      229        12                          beta
Radon      230         ?                          beta
Radon      231         ?                          beta
Francium   228        38                          beta
Francium   229        50.2                        beta
Francium   230        19.1                        beta
Francium   231        17.6                        beta
Francium   232         5                          beta
Francium   233          .9                        beta
Radium     223    988000                          alpha
Radium     224    314000                          alpha
Radium     225   1290000                          beta
Radium     226      1600 year                     alpha
Radium     227      2550                          beta
Radium     228 182000000                          beta
Radium     229       240                          beta
Radium     230      5580                          beta
Radium     231       103                          beta
Radium     232       250                          beta
Radium     233        30                          beta
Radium     234        30                          beta

Fission reactors
Technical detail

Actinides

Half life

The actinides are the elements from actinium to lawrencium. None are stable but many are long-lived.


Neutron transmutation

Neutron capture transmutes an isotope one space to the right and beta decay transmutes an isotope one space up.

The most massive nuclei that exist naturally are thorium-232, uranium-235, or uranium-238. All are unstable but have half lives larger than 700 million years. The road starts with these isotopes and then adding neutrons transmutes them according to the orange lines. The road forks at beta isotopes, which can either beta decay or capture a neutron.

The end of the road is fermium. Neutrons can't further increase the proton number because no fermium isotopes on the road beta decay. The road goes as far as fermium-258, which has a half life of .00037 seconds and spontaneously fissions. Producing heavier isotopes requires an accelerator or an extreme neutron flux (such as occurs in a fission bomb).

Most of the long-lived isotopes are on the neutron road, the most significant exceptions being neptunium-236 and berkelium-247. These isotopes can be reached by alpha decay, which moves an isotope 2 spaces down and 4 to the left.

Americium-242m (half live 141 years) is an excited state of Americium-242 (half life .0018 years) with a high thermal neutron capture cross section.

The thermal neutron capture cross section of Americium-241 to Americium-242 is 748 barns, and to Americium-242m is 83.8 barns.


Neutron capture

Transmutation rate is proportional to the neutron capture cross section. In order to move rightward on the road the isotope has to have a large neutron capture cross section and it has to have a large half life. This is true everywhere on the road except for curium-249, and so all the long-lived isotopes on the road are easily created, except for curium-250.

The road has a bottleneck at curium-246, which is the isotope with the lowest capture cross section (1.36 barns). The capture cross section of curium-248 is also low (2.49 barns). Traffic slows down here and all the isotopes further down the road have to wait for curium-246 and curium-248.

To create curium-250 you start with curium-248 and add a neutron to produce curium-249. Curium-249 has a half life of 64 minutes and you have to hope it captures a neutron before the decay.


Fission by thermal neutrons

The fission cross section is for thermal neutrons with a Maxwellian spectrum centered at .025 eV. The isotopes with large fission cross sections are:

                Thermal  Critical  Half life
                neutron    mass
                fission
                 barns      kg       years

Americium-242m   6686      11         141
Californium-251  4801       5.5       900
Einsteinium-254  2900       9.9          .75
Neptunium-236    2800       6.8    154000
Curium-245       2161      10        8500
Californium-249  1665       6         351
Plutonium-241     937      12          14.3
Plutonium-239     748      10       24100
Curium-243        690       8          29.1
Uranium-235       538      52   704000000
Uranium-233       468      15      159200


Fast fission


Critical mass

                  Fast     Crit   Crit  Half life        Fast      Fast
                 neutron   mass   diam                 neutrons   capture
                 fission                               /fission
                  barns     kg     cm     years                    barns

Californium-252     2.32     2.73                         4.30 
Californium-251     1.28     5.46            900          4.56       .63r
Californium-249     1.74     6               351           *
Curium-247          1.86     7.0                           *
Neptunium-236                7            154000           *
Curium-243          2.43     8                29.1        3.70        .4
Plutonium-238       1.994    9.5                          3.148
Einsteinium-254              9.89               .75        *
Curium-245          1.75    10              8500          4.0         .4
Plutonium-239       1.800   10             24100          3.123
Americium-242m      1.83    10               141          3.53        .6
Plutonium-241       1.648   12                14.3        3.142
Curium-244          1.73    15                            3.52        .8
Uranium-233         1.946   15            159200          2.649
Uranium-235         1.235   52         704000000          2.606
Plutonium-240       1.357   40                            3.061
Curium-246          1.25    45                            3.49        .4
Neptunium-237       1.335   60                            2.889      1.8
Berkelium-247               75.7
Plutonium-242       1.127   80                            3.07
Americium-241       1.378   60                            3.457      2.0
Berkelium-249              192                            3.74 
Americium-243        .2i   200                            3.45       1.8
Einsteinium-254m

Transmutation rate

Isotopes with a neutron capture cross section of 1 barn or more can be transmuted on a timescale of 10 years. Isotopes with a cross section smaller than this can't be practically transmuted.

To calculate the transmutation rate,

Neutron flux       =  F         = 10-8  neutrons/barn/second
Neutron capture    =  A         =    10  barns
Transmutation rate =  R  =  FA  =  10-7  transmutations/second  =  3.2 transmutations/year

Fission data

If a nucleus is hit with a pulse of neutrons then the probability that a fission occurs is:

Thermal neutron fission cross section =  A  =  6400 barns = 6.4⋅10-25 meters2   For Americium-242m
Neutron pulse magnitude               =  F  =  1020 neutrons/meter2
Fission probability                   =  P  =  AF  =  6.4⋅10-5 fissions

Most useful actinides

Actinides are useful for:

*) Neutron-induced fission
*) Radioactivity heat
*) Spontaneous fission

All of these properties are useful for spacecraft. The most useful actinides are:

                   Half life   Neutron  Spontaneous  Radioactivity
                               fission    fission
                     years      barns    Watts/kg      Watts/kg

Uranium     233       159200       468
            235    704000000       538
Plutonium   238           87.7                            818
            239        14100       748
            241           14.3     937                   4315
Americium   241          432
            242m         141      6686
Curium      243           29.1     690                   2666
            244           18.1                           4014
            245         8500      2161
            246         4730
            247     15700000
            248       340000                     .64         .81
            250         9000                  240         241
Berkelium   249             .90
Californium 248             .91                86       86209              Off-road
            249          351      1665
            250           13.08               158        5778
            251          900      4801
            252            2.64             31227       58470
            253             .049
            254             .166         15896000    15897000
Einsteinium 254             .75   2900
Fermium     257             .275     ?      20000      279000

Actinide content of spent fuel

                 After     Before
                  ppt       ppt

U-234                .2
U-235              10.3      33
U-236               4.4
U-238             943       967
Pu-238               .18
Pu-239              5.7
Pu-240              2.21
Pu-241              1.19
Pu-242               .49
Np-237               .43
Am-241               .22
Am-242               .0007
Am-243               .10
Cm-242               .00013
Cm-243               .00032
Cm-244               .024

Fission products   35
Tc-99                .81

Neutron flux
                 Neutron flux (Neutrons/cm2/second)

Power reactor          5e13
High-flux reactor      6e15
Cosmological s-process  e16
Cosmological r-process  e27
Fission bomb            e31

Actinide table

                Thermal   Fast    Crit  Crit  Half life    Slow   Fast      SF     Therm  Fast   Fast    SF       SF
                neutron  neutron  mass  diam               neutr  neut     neut    capt   capt   inel
                fission  fission                           /fiss  /fiss    /fiss   barn   barn           W/kg   neut/s/kg
                 barns    barns    kg    cm     years

Thorium-232                 .078                                     2.16
Protactinium-231            .83                                      2.457
Uranium-232        80      2.013                                     3.296  2
Uranium-233       468      1.946   15           159200        2.48   2.649         73
Uranium-234          .407  1.223                                     2.578  1.8                                  3.9
Uranium-235       538      1.235   52        704000000        2.42   2.606  2.0   690                             .0057
Uranium-236          .042   .594                                     2.526  1.8                                  2.3
Uranium-238          .00001 .308                                     2.601  1.97    2.68                         5.51
Neptunium-236    2800       *       7           154000         *      *
Neptunium-237        .019  1.335   60                         2.54i  2.889  2              1.8                <.05
Neptunium-238    1243      1.45                       .0058   2.79i  2.99i                   .1
Plutonium-237    2100i                                .124     *      *
Plutonium-238      16.8    1.994    9.5             87.7      2.36   3.148  2.28  558                      1204000     Alpha
Plutonium-239     748      1.800   10            24100        2.87   3.123  2.9  1017.3                         10.1     Alpha
Plutonium-240        .030  1.357   40             6560               3.061  2.189                           478000
Plutonium-241     937      1.648   12               14.3      2.92   3.142        36                             <.8     Beta
Plutonium-242        .0026 1.127   80           373000               3.07   2.28                            805000
Plutonium-243     181i
Plutonium-244                                 80800000
Plutonium-245                                     8500
Americium-241       3.1    1.378   60                         3.12   3.457                 2.0              500
Americium-242    1322i     3.4i                                                             .7
Americium-242m   6686      1.83    10              141        3.26   3.53i  2               .6
Americium-243        .2     .2i   200                         3.20i  3.45i                 1.8
Americium-244    1528i     3.4i                                *      *                     .9
Americium-244m   1220i     3.4i                               3.14i  3.42i                  .8
Curium-241       2600      2.21                       .090
Curium-242          5      1.78                               2.54
Curium-243        690      2.43     8               29.1      3.43   3.70i                  .4
Curium-244          1.1    1.73    15               18.1      2.72?  3.52i        16.2      .8             3.24i(t)    Alpha
Curium-245       2161      1.75    10             8500        3.83   4.0         383        .4                         Alpha
Curium-246           .17   1.25    45                         2.93   3.49i                  .4             3.19i(t)
Curium-247         82      1.86     7.0       15700000        3.80    *           58                                   Alpha
Curium-248           .34   1.09                               3.13    *                                     .64
Curium-249                 1.21
Curium-250           *      .67                               3.30    *
Berkelium-247               *      75.7
Berkelium-249       1.0     *     192                         3.40   3.74i                             240
Berkelium-250     959i
Californium-246                                               3.1
Californium-248            1.32                                                                          86
Californium-249  1665      1.74     6              351        4.06    *     3.4   481.4
Californium-250   112      1.49                               3.51    *                                 158
Californium-251  4801      1.28     5.46           900        4.1    4.56        2839       .62  2.216                 Alpha
Californium-252    33      2.32     2.73             2.64     4.00i  4.30i  3.75   20.4               31227            Alpha
Californium-253  1138       *                                  *      *
Californium-254     2.001j 1.80                       .75     3.85    *
Einsteinium-253     2.51    *                                 4.7     *                              15.9M
Einsteinium-254  2900       *       9.89              .75     4.2     *
Einsteinium-254m 1840       *                                  *      *
Fermium-244                                                   4
Fermium-246                                                   4
Fermium-254
Fermium-255      3360i      *                                 4       *
Fermium-256                                                   3.63    *
Fermium-257         *       *                         .275    3.87    *                          20000
Nobelium-252                                                  4.2

                Thermal   Fast    Critical  Diam  Half life    Slow      Fast       SF       SF        Spontaneous
                neutron  neutron    mass                     neutrons  neutrons  neutrons             fission
                fission  fission                             /fission  /fission  /fission   W/kg       neutron/s/kg
                 barns    barns      kg             years

Fission energy

The prompt kinetic energy released by fission is:

           Fission energy (MeV)

Actinium        168
Thorium         172
Protactinium    177
Uranium         181
Neptunium       185
Plutonium       189
Americium       195
Curium          198
Berkelium       203
Californium     207

Isotopes


Actinides

The actinides are the elements from actinium to lawrencium. None are stable but many are long-lived.


Neutron transmutation

Neutron capture transmutes an isotope one space to the right and beta decay transmutes an isotope one space up.

The most massive nuclei that exist naturally are thorium-232, uranium-235, or uranium-238. All are unstable but have half lives larger than 700 million years. The road starts with these isotopes and then adding neutrons transmutes them according to the orange lines. The road forks at beta isotopes, which can either beta decay or capture a neutron.

The end of the road is fermium. Neutrons can't further increase the proton number because no fermium isotopes on the road beta decay. The road goes as far as fermium-258, which has a half life of .00037 seconds and spontaneously fissions. Producing heavier isotopes requires an accelerator or an extreme neutron flux (such as occurs in a fission bomb).

Most of the long-lived isotopes are on the neutron road, the most significant exceptions being neptunium-236 and berkelium-247. These isotopes can be reached by alpha decay, which moves an isotope 2 spaces down and 4 to the left.

Americium-242m (half live 141 years) is an excited state of Americium-242 (half life .0018 years) with a high thermal neutron capture cross section.

The thermal neutron capture cross section of Americium-241 to Americium-242 is 748 barns, and to Americium-242m is 83.8 barns.


Neutron capture

Transmutation rate is proportional to the neutron capture cross section. In order to move rightward on the road the isotope has to have a large neutron capture cross section and it has to have a large half life. This is true everywhere on the road except for curium-249, and so all the long-lived isotopes on the road are easily created, except for curium-250.

The road has a bottleneck at curium-246, which is the isotope with the lowest capture cross section (1.36 barns). The capture cross section of curium-248 is also low (2.49 barns). Traffic slows down here and all the isotopes further down the road have to wait for curium-246 and curium-248.

To create curium-250 you start with curium-248 and add a neutron to produce curium-249. Curium-249 has a half life of 64 minutes and you have to hope it captures a neutron before the decay.


Fission by thermal neutrons

The fission cross section is for thermal neutrons with a Maxwellian spectrum centered at .025 eV. The isotopes with large fission cross sections are:

                Thermal  Critical  Half life
                neutron    mass
                fission
                 barns      kg       years

Americium-242m   6686      11         141
Californium-251  4801       5.5       900
Einsteinium-254  2900       9.9          .75
Neptunium-236    2800       6.8    154000
Curium-245       2161      10        8500
Californium-249  1665       6         351
Plutonium-241     937      12          14.3
Plutonium-239     748      10       24100
Curium-243        690       8          29.1
Uranium-235       538      52   704000000
Uranium-233       468      15      159200


Fast fission


Critical mass

                  Fast     Crit   Crit  Half life        Fast      Fast
                 neutron   mass   diam                 neutrons   capture
                 fission                               /fission
                  barns     kg     cm     years                    barns

Californium-252     2.32     2.73                         4.30 
Californium-251     1.28     5.46            900          4.56       .63r
Californium-249     1.74     6               351           *
Curium-247          1.86     7.0                           *
Neptunium-236                7            154000           *
Curium-243          2.43     8                29.1        3.70        .4
Plutonium-238       1.994    9.5                          3.148
Einsteinium-254              9.89               .75        *
Curium-245          1.75    10              8500          4.0         .4
Plutonium-239       1.800   10             24100          3.123
Americium-242m      1.83    10               141          3.53        .6
Plutonium-241       1.648   12                14.3        3.142
Curium-244          1.73    15                            3.52        .8
Uranium-233         1.946   15            159200          2.649
Uranium-235         1.235   52         704000000          2.606
Plutonium-240       1.357   40                            3.061
Curium-246          1.25    45                            3.49        .4
Neptunium-237       1.335   60                            2.889      1.8
Berkelium-247               75.7
Plutonium-242       1.127   80                            3.07
Americium-241       1.378   60                            3.457      2.0
Berkelium-249              192                            3.74 
Americium-243        .2i   200                            3.45       1.8
Einsteinium-254m

Transmutation rate

Isotopes with a neutron capture cross section of 1 barn or more can be transmuted on a timescale of 10 years. Isotopes with a cross section smaller than this can't be practically transmuted.

To calculate the transmutation rate,

Neutron flux       =  F         = 10-8  neutrons/barn/second
Neutron capture    =  A         =    10  barns
Transmutation rate =  R  =  FA  =  10-7  transmutations/second  =  3.2 transmutations/year

Fission data

If a nucleus is hit with a pulse of neutrons then the probability that a fission occurs is:

Thermal neutron fission cross section =  A  =  6400 barns = 6.4⋅10-25 meters2   For Americium-242m
Neutron pulse magnitude               =  F  =  1020 neutrons/meter2
Fission probability                   =  P  =  AF  =  6.4⋅10-5 fissions

Most useful actinides

Actinides are useful for:

*) Neutron-induced fission
*) Radioactivity heat
*) Spontaneous fission

All of these properties are useful for spacecraft. The most useful actinides are:

                   Half life   Neutron  Spontaneous  Radioactivity
                               fission    fission
                     years      barns    Watts/kg      Watts/kg

Uranium     233       159200       468
            235    704000000       538
Plutonium   238           87.7                            818
            239        14100       748
            241           14.3     937                   4315
Americium   241          432
            242m         141      6686
Curium      243           29.1     690                   2666
            244           18.1                           4014
            245         8500      2161
            246         4730
            247     15700000
            248       340000                     .64         .81
            250         9000                  240         241
Berkelium   249             .90
Californium 248             .91                86       86209              Off-road
            249          351      1665
            250           13.08               158        5778
            251          900      4801
            252            2.64             31227       58470
            253             .049
            254             .166         15896000    15897000
Einsteinium 254             .75   2900
Fermium     257             .275     ?      20000      279000

Actinide content of spent fuel

                 After     Before
                  ppt       ppt

U-234                .2
U-235              10.3      33
U-236               4.4
U-238             943       967
Pu-238               .18
Pu-239              5.7
Pu-240              2.21
Pu-241              1.19
Pu-242               .49
Np-237               .43
Am-241               .22
Am-242               .0007
Am-243               .10
Cm-242               .00013
Cm-243               .00032
Cm-244               .024

Fission products   35
Tc-99                .81

Neutron flux
                 Neutron flux (Neutrons/cm2/second)

Power reactor          5e13
High-flux reactor      6e15
Cosmological s-process  e16
Cosmological r-process  e27
Fission bomb            e31

Actinide table

                Thermal   Fast    Crit  Crit  Half life    Slow   Fast      SF     Therm  Fast   Fast    SF       SF
                neutron  neutron  mass  diam               neutr  neut     neut    capt   capt   inel
                fission  fission                           /fiss  /fiss    /fiss   barn   barn           W/kg   neut/s/kg
                 barns    barns    kg    cm     years

Thorium-232                 .078                                     2.16
Protactinium-231            .83                                      2.457
Uranium-232        80      2.013                                     3.296  2
Uranium-233       468      1.946   15           159200        2.48   2.649         73
Uranium-234          .407  1.223                                     2.578  1.8                                  3.9
Uranium-235       538      1.235   52        704000000        2.42   2.606  2.0   690                             .0057
Uranium-236          .042   .594                                     2.526  1.8                                  2.3
Uranium-238          .00001 .308                                     2.601  1.97    2.68                         5.51
Neptunium-236    2800       *       7           154000         *      *
Neptunium-237        .019  1.335   60                         2.54i  2.889  2              1.8                <.05
Neptunium-238    1243      1.45                       .0058   2.79i  2.99i                   .1
Plutonium-237    2100i                                .124     *      *
Plutonium-238      16.8    1.994    9.5             87.7      2.36   3.148  2.28  558                      1204000     Alpha
Plutonium-239     748      1.800   10            24100        2.87   3.123  2.9  1017.3                         10.1     Alpha
Plutonium-240        .030  1.357   40             6560               3.061  2.189                           478000
Plutonium-241     937      1.648   12               14.3      2.92   3.142        36                             <.8     Beta
Plutonium-242        .0026 1.127   80           373000               3.07   2.28                            805000
Plutonium-243     181i
Plutonium-244                                 80800000
Plutonium-245                                     8500
Americium-241       3.1    1.378   60                         3.12   3.457                 2.0              500
Americium-242    1322i     3.4i                                                             .7
Americium-242m   6686      1.83    10              141        3.26   3.53i  2               .6
Americium-243        .2     .2i   200                         3.20i  3.45i                 1.8
Americium-244    1528i     3.4i                                *      *                     .9
Americium-244m   1220i     3.4i                               3.14i  3.42i                  .8
Curium-241       2600      2.21                       .090
Curium-242          5      1.78                               2.54
Curium-243        690      2.43     8               29.1      3.43   3.70i                  .4
Curium-244          1.1    1.73    15               18.1      2.72?  3.52i        16.2      .8             3.24i(t)    Alpha
Curium-245       2161      1.75    10             8500        3.83   4.0         383        .4                         Alpha
Curium-246           .17   1.25    45                         2.93   3.49i                  .4             3.19i(t)
Curium-247         82      1.86     7.0       15700000        3.80    *           58                                   Alpha
Curium-248           .34   1.09                               3.13    *                                     .64
Curium-249                 1.21
Curium-250           *      .67                               3.30    *
Berkelium-247               *      75.7
Berkelium-249       1.0     *     192                         3.40   3.74i                             240
Berkelium-250     959i
Californium-246                                               3.1
Californium-248            1.32                                                                          86
Californium-249  1665      1.74     6              351        4.06    *     3.4   481.4
Californium-250   112      1.49                               3.51    *                                 158
Californium-251  4801      1.28     5.46           900        4.1    4.56        2839       .62  2.216                 Alpha
Californium-252    33      2.32     2.73             2.64     4.00i  4.30i  3.75   20.4               31227            Alpha
Californium-253  1138       *                                  *      *
Californium-254     2.001j 1.80                       .75     3.85    *
Einsteinium-253     2.51    *                                 4.7     *                              15.9M
Einsteinium-254  2900       *       9.89              .75     4.2     *
Einsteinium-254m 1840       *                                  *      *
Fermium-244                                                   4
Fermium-246                                                   4
Fermium-254
Fermium-255      3360i      *                                 4       *
Fermium-256                                                   3.63    *
Fermium-257         *       *                         .275    3.87    *                          20000
Nobelium-252                                                  4.2

                Thermal   Fast    Critical  Diam  Half life    Slow      Fast       SF       SF        Spontaneous
                neutron  neutron    mass                     neutrons  neutrons  neutrons             fission
                fission  fission                             /fission  /fission  /fission   W/kg       neutron/s/kg
                 barns    barns      kg             years

Fission energy

The prompt kinetic energy released by fission is:

           Fission energy (MeV)

Actinium        168
Thorium         172
Protactinium    177
Uranium         181
Neptunium       185
Plutonium       189
Americium       195
Curium          198
Berkelium       203
Californium     207

Fission reactors
Technical detail

Moderator

Fission cross section
Scattering and capture cross sections

The slower the neutron, the larger the fission cross section. Fission produces 2 or 3 high-energy neutrons, or "fast" neutrons, which are then slowed down by the moderator.

The lighter the nucleus, the more effective it is in slowing down neutrons. However the lightest nucleus, the proton, is prone to capturing neutrons, hindering its effectiveness as a moderator. Deuterium rarely captures neutrons and is the best moderator.

Neutron colliding with a proton
Slowing down neutrons
A gas in thermal equilibrium

Moderator nucleus, mass number         =  A
Logarithmic energy loss per collision  =  L  = 1 - ½ (A-1)2 A-1 [ln(A-1) - ln(A+1)]  ~  2/(A+⅔)
Neutron scattering cross section       =  S
Neutron capture cross section          =  A
Slowing power                          =  s  =  LS
Moderating power                       =  M  =  LS/A

                                     Thermal  Thermal                                               Fast
             Moderating     # of     neutron  neutron  Log energy loss  Slowing  Diffuse   Stop    neutron
               power     collisions  scatter  capture   per collision    power   meters   meters   scatter
                                      barns    barns
Hydrogen         60         18        20        .333        1            20                          3.94
Deuterium     10700         25         7.64     .000519      .726         5.55                       2.54
Tritium                                3.03     .000006
Light water      71         16                  .222         .92                  .028     .0051
Heavy water    5670         29                  .00041
Helium           51         42         1.34     .0075
Lithium                                1.37   70.5
Lithium-6                               .97  940
Lithium-7                              1.4      .0454
Beryllium       173         86         7.63     .0092        .208         1.59
Be2C
BeO
Boron              .00086  105         5.24  767
Carbon          229        114         5        .0035        .159          .80    .56      .0275
Oxygen         2680        150         4.23     .00019       .121          .51
Fluorine                               4.02     .0096
Neon                                            .04
Sodium                                 3.28     .53
Lead                                  11.12     .171
Bismuth                                9.16     .0338
Thorium                                        7.37
Uranium            .0092  2172                 7.57          .0084
Uranium-235                           14     681             .0084
Uranium-238        .0092  2172         8.87    2.68          .0084
Plutonium-239                          7.7  1017
Plutonium-240                          1.54  290
Plutonium-241
Plutonium-242                          8.2    18.5
Li2BeF4

Coolant

The choices of coolant are liquid metal, liquid salt, and noble gas.

Liquid metal is a good coolant for high thermal conductivity and high density. An ideal metal coolant has a low melting point, a high boiling point, doesn't absorb neutrons, is uncorrosive, and is nonreactive with oxygen. The best choices are lead and bismuth. The metals with low melting points are:

          Neutron capture   Melt   Boil  Boil-Melt  Heat Cap  Oxygen  Cost   Weaknesses
              barns          K      K        K      kJ/K/m3   immune  $/kg

Bismuth            .034      545   1837    1292      1170      Yes       18   Corrosive
Lead               .171      601   2022    1421      1460      Yes        2
Rubidium           .38       312    961     649                No     12000
Sodium             .53       371   1156     785      1190      No       250
Tin                .626      505   2875    2370                Yes       22   Liquid tin forms crusts that obstruct flow
Cerium             .6       1068   3716    2648                No         2.5
Gallium           2.9        303   2673    2370                Yes      280
Thallium          3.43       577   1746    1169                Yes      480
Lanthanum         9.0       1193   3737    2544                No         3

Water                        273    373     100                Yes
Heavy water                  277                               Yes
LiF                .028     1118   4230                        Yes
BeF2               .0095     827   2190                        Yes
Li2BeF4            .020      732   4540                        Yes

Lead-208           .000230   601   2022    1421                Yes     High
Lithium-7          .0454     454   1603    1149      1910      No      High
Cerium-140         .571     1068   3716    2648                       High
Lanthanum-139     8.94      1193   3737    2544                High

For gas coolant, helium is preferred. The only 2 gases with low neutron capture and low corrosivity are helium and neon, and helium is preferred for its higher conductivity and higher heat capacity per volume.

Gas cooled reactors can have extreme temperatures. The temperature is limited only by the structural material.

     Neutron capture  Heat Capacity
         barns           kJ/K/m3

Helium      .007          8.51
Neon        .04
Argon       .675
Nitrogen   1.91
Xenon     23.9
Krypton   25

For liquid salt coolant, the only oxidant with a low neutron capture cross section is fluorine.

       Neutron capture
           barns

Fluorine      .0096
Chlorine    35.5
Bromine      6.8
Iodine       6.2

The best flouride salt is "Flibe", a salt of lithium, beryllium, and flourine. It has a low neutron capture cross section and a low melting point. Most flouride salts are disqualified because of their high melting point. The choices for the positive ion in the salt are:

       Neutron capture  Fluoride  Flouride
           barns        Melt (K)  Boil (K)

Deuterium    .000519      190       293       Highly corrosive
Beryllium    .0092        827      1442
Li2BeF4      .033         732      1703
Lithium-7    .0454       1118      1949
Magnesium    .063        1536      2530
Aluminum     .232        1560
Rubidiuim    .38         1068      1681
Sodium       .53         1266      1977
Potassium   2.1          1131      1775
Caesium    29             976      1524
The only fluorides with a low melting point and a high boiling point are lithium flouride and Flibe.
Structural materials

A good structural material has a low neutron capture cross section, a high melting point, and a low price. The best choice is zirconium. The contenders are:

             Neutron   Element  Carbide  Cost
             capture    melt     melt
              barns       K        K     $/kg

Beryllium        .0092    827   2370      850
Zirconium        .184    2128   3805       25
Platinum         .96     2041      -    24000
Niobium         1.15     2750   3881       40
Ruthenium       2.56     2607      -     5600
Iron            2.56     1811    996         .3
Molybdenum      2.6      2896   2960       24
Chromium        3.1      2180   2168        2.3
Osmium         15        3306      -    12000
Tungsten       18.3      3695   3058       50
Tantalum       20.6      3290   4150      160
Hafnium       104        2506   4201      500

Diamond          .0035   2800      -
Zirconium-90     .0107   2128   3805
Molybdenum-92    .0614   2896   2960
Ruthenium-104    .31     2607      -
Platinum-196     .72               -
Tungsten-184    1.70     3695   3103
Osmium-192      3.12     3306      -
Hafnium-180    12.92     2506   4201

Control rod

A control rod should have a large neutron capture cross section and a large melting point (unless it's a gas). The contenders are:

         Neutron capture   Melt
              barns         K

Gadolinium       49000     1585
Samarium          5922     1345
Europium          4600     1099
Cadmium           2450      594
Dysprosium         920     1680
Boron              767     2349
Iridium            425     2719
Mercury            374      234

Krypton             25      116
Xenon               23.9    161
Argon                 .68    84
Neon                  .04    25

Gadolinium-157  250000     1585
Gadolinium-155   61000     1585
Samarium-149     42080     1345
Cadmium-113      20600      594
Europium-151      9100     1099
Dysprosium-164    2840     1680

A gas such as krypton has the potential for fast action. The reactor can be kept under vacuum and then if krypton is released, it swiftly fills the reactor.


Compact lightweight fission reactor

For the fission fuel, use Californium-251 for its high neutron capture cross section and high neutrons per fission.

                                 Neutron capture    Melt   Boil
                                      barns          K      K

Moderator:     ZrD4
               Be2C                                 2370
               BeO                                  3010
               Be                                   1560
               Diamond
Coolant:       Lead-208                  .000230     601   2022
               Li2BeF4                   .020        732   4540
Structure:     Molybdenum-92             .0614      2896   2960
               Zirconium-90 carbide      .0107      3805      -
               Diamond                   .0035      2800      -
Control rod:   Gadolinium-157      250000           1585
               Iridium-191            954           2719
               Krypton-83             185            116
Fission fuel:  Californium-252         33                             2.64   Neutrons/fission=3.76   4.30
               Californiuim-251      4801                           900      Neutrons/fission=4.1    4.56
               Einsteinium-254       2900                              .75   Neutrons/fission=4.2
               Americium-242m        6686                           141      Neutrons/fission=3.26   3.53
               Californium-254          2.00                           .166  Neutrons/fission=3.85
               Fermium-255           3360                                    Neutrons/fission=4
               Einsteinium-253          2.51                                 Neutrons/fission=4.7

Abundance
Abundance of elements in the sun, indicated by dot size

Blue elements are unstable with a half life much less than the age of the solar system.

The only elements heavier than Bismuth that can be found on the Earth are Thorium and Uranium, and these are the only elements that can be tapped for fission energy.

Natural Thorium is 100% Thorium-232
Natural Uranium is .72% Uranium-235 and 99.3% Uranium-238.
Plutonium doesn't exist in nature.

           Protons  Neutrons  Halflife   Critical   Isotope
                              (106 yr)   fraction

Thorium-232    90    142      14000          -       1.00     Absorbs neutron -> U-233
Uranium-233    92    141           .160     16        -       Fission chain reaction
Uranium-235    92    143        700         52        .0072   Fission chain reaction
Uranium-238    92    146       4500          -        .9927   Absorbs neutron -> Pu-239
Plutonium-238  94    144           .000088   -        -       Produces power from radioactive heat
Plutonium-239  94    145           .020     10        -       Fission chain reaction
The elements that can be used for fission energy are the ones with a critical mass: Uranium-233, Uranium-235, and Plutonium-239. Uranium-233 and Plutonium-239 can be created in a breeder reactor.
Thorium-232  +  Neutron  ->  Uranium-233
Uranium-238  +  Neutron  ->  Plutonium-239
The "Fission" simulation at phet.colorado.edu illustrates the concept of a chain reaction.

Natural uranium is composed of .7% Uranium-235 and the rest is Uranium-238. Uranium-235 can be separated from U-238 using centrifuges, calutrons, or gas diffusion chambers. Uranium-235 is easy to detonate. A cannon and gunpowder gets it done.

Plutonium-239 is difficult to detonate, requiring a perfect spherical implosion. This technology is beyond the reach of most rogue states.

Uranium-233 cannot be used for a bomb and is hence not a proliferation risk.

Plutonium-238 emits alpha particles, which can power a radioisotope thermoelectric generator (RTG). RTGs based on Plutonium-238 generate 540 Watts/kg and are used to power spacecraft.

Teaching simulation for nuclear isotopes

Energy

The fission of uranium-233, uranium-235, and plutonium-239 yields similar energies. The "reactor heat" column is the energy yield per nucleus in a reactor. Energies in MeV:

             Fission    Prompt   Prompt  Prompt   Decay   Decay    Anti-    Reactor
            fragments  neutrons  gammas  neutron  betas   gammas  neutrinos  heat
                                         capture
Uranium-233    168.2      4.9     7.7     9.1      5.2     5.0      6.9      200.1
Uranium-235    169.1      4.8     7.0     8.8      6.5     6.3      8.8      202.5
Plutonium-239  175.8      5.9     7.8    11.5      5.3     5.2      7.1      211.5

Generating fission fuel in a breeder reactor

Creating Plutonium-239 and Uranium-233:

Uranium-238 + Neutron  ->  Plutonium-239
Thorium-232 + Neutron  ->  Uranium-233

Detail:

Uranium-238 + Neutron  ->  Uranium-239
Uranium-239            ->  Neptunium-239 + Electron + Antineutrino    Halflife = 23 mins
Neptunium-239          ->  Plutonium-239 + Electron + Antineutrino    Halflife = 2.4 days

Thorium-232 + Neutron  ->  Thorium-233
Thorium-233            ->  Protactinium-233 + Electron + Antineutrino   Halflife = 22 mins
Protactinium-233       ->  Uranium-233      + Electron + Antineutrino   Halflife =

Hydrogen

The goal is to maximize the number density of hydrogen atoms, and the molecule that achieves this is TaH5.

Density                =  D         =15100  kg/meter3
Hydrogen number        =  N         =    5
Hydrogen mass          =  m         =    1  AMU  =  1.66⋅10-27 kg
Molecule mass          =  M         =  182  AMU  =  3.02⋅10-25 kg
Hydrogen number density=  n  = ND/M =  2.50⋅1029 atoms/meter3
Hydrogen mass density  =  d  = NDm/M=  415  kg/meter3

For various molecules containing hydrogen,

       H mass     Density       Melt     Boil    Mass    Heat capacity
       density    kg/meter3       K        K      AMU

TaH5        415      15100         ?            182
B2H6        247       1131       108.3   180.7   27.67
ZrH4        220      ~5200         ?             95.3
AlH3        149       1477       378d            30.0      40.2  mol
UH3         137      10950       773d           241.1
HfH2        127      11400       673            180.5
NbH5                                             97.9
ZrH2        120       5560                       93.2
BeH2        119        650       523d            11.03     30.12 mol
H2O         112       1000       273     373     18.016
MgH2        111       1450                       26.32     35.4  mol
C3H8        110        600        85.5  231.1
C2H6        110        545        90.4  184.6
CH4         107        423        90.7  111.7
C4H10       104        600       136    274
LiH          99        780       962    1270      7.95   3510
LiAlH4       97        917       423d            37.95     86.4 mol
B5H9         89        618       226.3  333.2    63.12
Liquid H2    70         70        14.0    20.3    2.016    28.8  mol
ZrH          64       5900                       92.2
TiH2                  3760       623             49.88
Ge2H6                            164    304     151.3
AlLi3H6                                          53.85
PuH2                                            246
K2ReH9                                          273.5                   Potassium nonahydridorhenate
PuH3


Neutron shield

A fission reactor can be surrounded by neutron shield that captures all neutrons, so that they don't escape to the environment. Neutrons can make materials radioactive. The shield should consist of an element with the following properties:
Large neutron capture cross section
Cheap
No radioactive isotopes should be produced after neutron capture.


Elements

Among the elements that cost less than 20 $/kg, the neutron absorption cross sections are:

           Neutron capture   Cost   Quality
                barns        $/kg   barns/$

Gadolinium        49000      29    2450       Europium-154       8.59       Fraction=.0020
Cadmium            2450       2.7  1220       Caesium-134        2.06
Samarium           5922      13.6   740       Problems
Boron               767       3.7   183       Carbon-14       5730
Chlorine             35.5     1.5    24       Chlorine-36
Europium           4600     287      15
Dysprosium          920     390      11.5
Iron                  2.56     .13    8.5     Cobalt-60
Manganese            13.3     2.2     5.8     Cobalt-60
Neodymium            49      96       1.96
Copper                3.78    7        .61    Krypton-85
Titanium              6.09   17        .61    Cobalt-60
Vanadium              5.08   28        .42    Cobalt-60
Iodine                6.2    35        .39
Tungsten             18.3    32        .37
Lithium              70.5    70        .35
Indium              194     180        .26
Erbium              160      26        .03
Mercury             374      50      23
Thallium              3.43 4200
Lead                   .171   2.1      .086

Nickel                4.49   15               Nickel-59
Chromium              3.1     2.3             Cobalt-60
Molybdenum            2.6    24
Potassium             2.1
Nitrogen              1.91
Zinc                  1.11    2
Sodium                 .53
Sulfur                 .53                    Chlorine-36
Calcium                .43
Hydrogen               .333
Aluminum               .232   1.7
Silicon                .171
Fluorine               .0096
Magnesium              .063
Carbon                 .0035
Oxygen                 .00019

Neutron stopping length

The stopping length of a neutron in Americium-242m is:

Cross section           =  A           =      6686  barns
Atomic mass unit        =  m           = 1.660e-27  kg
Nucleons                =  q           =       242
Nucleus mass            =  M  =  m q   =  4.02e-25  kg
Density                 =  D           =     12000  kg/meter3
Atom density            =  N  =  D/M   =   2.99e28  atoms/meter3
Neutron stopping length =  X  = 1/(AN) =   5.00e-5  meters
Atoms/Area              =  n  =  NX    =   1.50e24  atoms/meter2
Mass/Area               =  H  =  M n   =        .6  kg/meter2

The only way to exceed reactor flux is with spallation. An accelerator fires high-energy protons at a target with heavy nuclei, and the proton ejects neutrons from the nuclei.



Spallation            e17
Reactor               e15
R process             e32
HFIR                  4e14
S process             e11
Californium-252       e9
Alpha-Beryllium       e8
Fusor                 e5       .3 Mn/s
Light ion accelerator
Proton energy per neutron     =  50  MeV/neutron


Neutron capture time

Neutron capture cross section  =  A         =    1  barn  =  e-28 meter2
Neutron flux                   =  F         =  e22  neutrons/meter2/s
Neutron capture rate           =  R  =  AF  =  e-6  neutrons/second  =  32 neutrons/year



Neutron capture cross section   =  A           =   1.e-28  meter2   =   1  barn
Tungsten atom mass              =  M           =3.053e-25  kg
Tungsten density                =  D           =    19300  kg/meter3
Tungsten number density         =  n  =  D/M   =   6.3e28  atoms/meter3
Neutron path length             =  L  = (nA)-1 =     .159  meters

Chilled neutrons

The neutron capture cross section increases with decreasing neutron temperature.

Room temperature            =  T          =  300  Kelvin
Cold neutron temperature    =  t          = .005  Kelvin
Cross section amplification =  Q  = (T/t) =  245


Neutron value

Neutron mass        =  M  =1.675e-27  kg
Energy per neutron  =  E  =       50  MeV  =  8.0e-12 Joule
Energy cost         =  e  =       40  MJoule/$
Neutron cost/mass   =  C  =      120  M$/kg

Neutron value
                  barn    second

Tungsten-181                          < 1
Tungsten-188             .00270       > 2
Osmium-194        3.12   .00343       > 2
Helium-3
Hafnium-172                           < 2
Tantalum-179                          < 1



Energy per proton    =   e  =        .8  GeV/proton     =  1.28e-10  Joules/proton
Current              =   I  =     .0002  Coulombs/second
Proton charge        =   q  = 1.602e-19  Coulombs
Protons per time     =   R  =   1.25e15  Protons/second
Power                =   P  =  Q  =  Re =  .16 MWatts

Nuclear spallation

Neutron yield

The neutron yield for a 1 GeV proton is:

           Neutrons/Proton

Aluminum        2.2
Iron            4.1
Zirconium       6.3
Lead           11.9
Tantalum       12.7
Tungsten       13.1
Thorium        18
Uranium-238    21.4

Nucleus mass number  =  M  =  184
Proton energy        =  E  =    1  GeV
Neutron yield        =  .10 * (A+20) (E-.12)  =  18

                Energy (GeV)

Secondary protons    212
Primary protons      194
Neutrons              26
Neutral pions         40
Charged pions         15
Heavy particles       15         More than one nucleon
Gammas                13
Muons                  3.6

High-temperature materials

Melting points for oxides, carbides, nitrides, and borides:

              Element  Oxide   Carbide  Nitride  Boride  Hydride  Fluoride  Heat cap
              Kelvin   Kelvin  Kelvin   Kelvin   Kelvin  Kelvin    Kelvin  KJoules/kg

Hydrogen                                                     -               14.30
Helium                                                                        5.19
Lithium           454   1711     823                                          3.58
Beryllium        1560   2780    2370     2470              523                1.82
Boron            2349    723    3036     3246              108
Carbon           3800              -                                           .709
Oxygen                     -                               273
Sodium            371                                                         1.23
Lead                                                                           .129
Magnesium         923   3125       ?              1100     600                1.02
Aluminum          933   2345    1770                       423                 .897
Silicon          1687   1986    3100                        88
Sulfur                                                               222
Scandium         1814                                    unstable
Titanium         1941   2116    3430     3200     3500     623
Vanadium         2183    963    3080     2320     2723*
Chromium         2180   2708    2168              2443*
Manganese
Iron             1811            996              1570
Cobalt           1768   2206                      1733*
Nickel           1728                             1398*
Copper           1358
Zinc                                                     unstable
Selenium                                                             239
Strontium        1050   2804             1470     2508
Zirconium        2128   2988    3805     3225     3323*   1070
Niobium          2750   2188    3881     2846     3323*                                       NbO2
Molybdenum       2896   1370    2960              2643*              291
Technetium       2430    393                                         311
Ruthenium        2607   1470                     exist               327
Rhodium          2237   1370                                         343
Palladium        1828
Silver           1234
Cadmium           594
Tin                                                      unstable
Tellurium                                                            234
Xenon                                                                224
Caesium           302    763
Lanthanum                                         2480
Gadolinium       1585   2690
Samarium         1345   2608
Lutetium         1925                                                                   3675
Hafnium          2506           4201              3520
Tantalum         3290   2145    4150      3360    3373
Tungsten         3695   1970    3103     exist    2943               276
Rhenium          3459   1273     dne              2670               292
Osmium           3306    773  future       dne   exist               307
Iridium          2719   1370                                         317
Platinum         2041                                                335
Lead                                                     unstable               .129
Bismuth                                                  unstable
Radium            973

              Element  Oxide   Carbide  Nitride  Boride  Hydride  Fluoride  Heat cap
              Kelvin   Kelvin  Kelvin   Kelvin   Kelvin  Kelvin    Kelvin  KJoules/kg
Actinium                                                                                3471
Thorium                                                                                 5061
Protactinium                                                                            4300
Uranium          1405   3138    2620      1170    2700               337                4404
Neptunium                                                            328                4273
Plutonium         912   3017                                         325                3505
Americium        1449   2478                                                            2880
Curium           1613   1992                                                            3383
Californium      1173   2023                                                            1743
Einsteinium      1133                                                                   1269
Fermium          1800

Diamond
Quartz
Graphite
Corundum         2317
Lead                                                     unstable               .129        1.46       11.34

              Element  Oxide   Carbide  Nitride  Boride  Hydride  Fluoride  Heat cap     Heat cap     Density    Boil
              Kelvin   Kelvin  Kelvin   Kelvin   Kelvin  Kelvin    Kelvin  KJoules/kg  KJoules/litre  gram/cm3

                   Melt    Boil   Density
                  Kelvin  Kelvin   g/cm3

HfCN                4400                   HfCN
TaHf carbide        4263          14.8     Ta4HfC5
Hafnium carbide     4201          12.2     HfC
Tantalum carbide    4150         ~15       TaC
Niobium carbide     3881           7.82    NbC
Zirconium carbide   3805   5370    6.73    ZrC
Carbon (graphite)   3800           2.15
Tungsten            3695   6203   19.2
Hafnium diboride    3520          10.5     HfB2
Zirconium diboride  3519           6.08    ZrB2
Titanium diboride   3500           4.52    TiB2
Rhenium             3459          21.0
Titanium carbide    3430   5090    4.93    TiC
Tantalum diboride   3373                   TaB2
Tantalum nitride    3360          14.3     TaN
Osmium              3306   5285   22.6
Tantalum            3290          16.7
Boron nitride       3246           2.1     BN
Titanium nitride    3200           5.22    TiN
Uranium oxide       3138          10.97    UO2
Magnesium oxide     3125   3870    3.6     MgO
Tungsten carbide    3103   6270   15.6     WC
Silicon carbide     3100           3.16    SiC
Vanadium carbide    3080           5.77    VC
Boron carbide       3036   3770    2.52    B4C
Plutonium oxide     3017   3070   11.5     PuO2
Molybdenum carbide  2960           8.90    MoC
Tungsten boride     2943                   W2B
Tungsten boride     2928                   WB
Molybdenum          2896          10.3
Strontium oxide     2804   3470    4.70    SrO
Beryllium oxide     2780   4170    3.01    BeO
Niobium             2750           8.57
Iridium             2719          22.6
Uranium diboride    2700          12.7     UB2
Uranium carbide     2620          13.63    UC
Ruthenium           2607          12.4
Strontium hexaboride2508           3.39    SrB6
Hafnium             2506          13.3
Lanthanum hexaboride2480           4.72    LaB6
Beryllium nitride   2470   2510    2.71    Be3N2
Technetium          2430          11
Beryllium carbide   2370           1.9     Be2C
Boron               2349           2.34
Aluminum oxide      2345   3250    3.99    Al2O3
Vanadium nitride    2320           6.13    VN
Sapphire            2300           4.0     Al2O3
Rhodium             2237          12.4
Vanadium            2183           6.0
Chromium            2180           7.15
Chromium carbide    2168   4070    6.68    Cr3C2
Tantalum oxide      2145           8.13    Ta2O5
Zirconium           2128           6.52
Cobalt oxide        2206           6.44    CoO
Titanium oxide      2116   3245    4.23    TiO2
Quartz              1986           2.65    SiO2
Tungsten oxide      1970          10.8     WO2
Titanium            1941           4.51
Palladium           1828          12.0
Scandium            1814           2.98
Iron                1811           7.86
Aluminum carbide    1770           2.93    Al4C3
Cobalt              1768   3200    8.90
Nickel              1728           8.91
Lithium oxide       1711   2870    2.01    Li2O
Silicon             1687           2.33
Curium              1613   3383   13.5
Iron boride         1570           7.15    FeB
Beryllium           1560           1.85
Americium           1449   2880   12
Uranium             1405   4404   19.0
Molybdenum dioxide  1370           6.47
Copper              1358           8.96
Silver              1234          10.5
Californium         1173   1743   15.1
Uranium nitride     1170          11.3     UN
Magnesium diboride  1100           2.57    MgB2
Strontium           1050   1650    2.64
Iron carbide         996                   Fe3C
Radium               973   2010    5.5
Aluminum             933           2.70
Magnesium            923           1.74
Plutonium            912   3505   19.82
Polonium             527   1235    9.3
Lithium carbide      823           1.3     Li2C2
Caesium oxide        763           4.65    Cs2O
Cadmium              594           8.65
Lithium              454            .53
Sodium               371            .97
Caesium              302    944    1.93
Tantalum hydride                  15.1     TaH
Hafnium hydride                   11.4     HfH2
Zirconium hydride   1070           5.6     ZrH2

High-temperature radioisotopes

            Power/Mass  Half life  Decay  Melt  Decay                        Side  Distance  Potholes
             Watt/kg      year      MeV         mode

Rhenium-184                .104                       5869           e+              <  1
Tungsten-188               .191    .349   3695  3695  6203  Metal    e-              >  2
Hafnium-181                .116           2506  4201  4876  Carbide  e-              >  1
Hafnium-175                .192           2506  4201  4876  Carbide  e+              >  1
Osmium-185                 .256                                      EC              >  1
Tungsten-181      9546     .332    .1877  3695  3695  6203  Metal    EC
Rhenium-184m               .463    .188                              IT or e+        <  1
Rhodium-102      67003     .567   1.268   2237        3968           e+ or e-
Ruthenium-106     1116    1.018    .0394  2607        4423           e-
Tantalum-179       991    1.82     .1056  3290  4150  5731  Carbide  EC              <  1
Hafnium-172       3210    1.87     .338   2506  4201  4876  Carbide  EC              <  2
Rhodium-101       4967    3.3      .542   2237        3968           EC              <  2
Osmium-194                6.02    2.33    3306        5285           e-              >  2     pothole 30.1 hours
Niobium-93m              16.13     .03077 2750  3881  5017  Carbide  Gamma           =  0
Hafnium-178m2     1401   31       2.446   2506  4201  4876  Carbide  Gamma           =  0
Platinum-193             50        .0568                             EC              >  1
Uranium-232       1035   68.9     5.414   1405  3138  4404  Oxide    Alpha
Niobium-91              680               2750  3881  5017  Carbide                  <  2

Plutonium-238      818   87.7     5.59     912  3017  3505  Oxide    Alpha
Plutonium-241     4315   14.4     4.90     912  3017  3505  Oxide    Alpha
Curium-243        2666   29.1     6.169   1613  1992  3383  Oxide    Alpha
Curium-244        4014   18.1     5.80    1613  1992  3383  Oxide    Alpha
Curium-250         241 8300       5.17    1613  1992  3383  Oxide    SF or Alpha
Cobalt-60        27300    5.27    2.82    1768  2206  3200  Oxide    e-, Gamma

Beryllium-7                .146                       2742           EC              <  2
Californium-252  58470    2.64    6.12    1173  2023  1743  Oxide    Alpha or SF
Californium-250   5779   13.1     6.02    1173  2023  1743  Oxide    Alpha or SF
Beryllium-7    2577000     .146    .862   1560  2780  2742  Oxide    EC
Titanium-44        295   63        .268   1941  3430  3560  Carbide  EC

Titanium-60              60.0                                        EC              <
Niobium-93m              16.13     .03077                            IT              >  0
Ruthenium-106             1.023                                      e-              >  2   105 is 4.44 hours
Rhodium-102                .567                                      e+ or e-
Rhodium-102m              3.742    .1408                             e+

Vanadium-49                .901                                      EC              <
Zirconium-95               .175                                                      >  1
Lutetium-173              1.37                                       EC              <
Iridium-192                .202                                      e- or EC        >  1
Lutetium-174              3.31                        3675           e+              <  1
Lutetium-174m1             .389    .171               3675           IT              <  1
Lutetium-177               .0182                                     e-              >  1
Lutetium-177m3             .439    .970                              e- or IT        >  1

High-temperature and low neutron absorption
               Melt    Neutron capture
              Kelvin       barn


Ta Hf carbide     4263   60
Hafnium carbide   4201  104
Tantalum carbide  4150   20
Niobium carbide   3881    1.15
Zirconium carbide 3805     .184
Diamond           3800     .0035
Tungsten          3695   18.3
Rhenium           3459   89.7
Osmium            3306   15
Tantalum          3290   20.6
Tungsten carbide  3103   18.3
Iridium           2719  425
Hafnium           2506  104
Molybdenum        2896    2.6
Niobium           2750    1.15
Ruthenium         2607    2.56
Technetium        2430   20
Rhodium           2237  145
Vanadium          2183    5.08
Chromium          2180    3.1
Zirconium         2128     .184
Platinum          2041     .96
Titanium          1941    6.09
Lutetium          1925   84
Palladium         1828
Fermium           1800
Curium            1613
Americium         1449
Uranium           1405
Californium       1173
Einsteinium       1133
Plutonium          912

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Data from Wikipedia unless otherwise specified.